Question

A hydrogen atom is in the 1s state at time t 0. At this time an external electric field of magnitude goe-T is applied along the z direction. Find the first-order probability that the atom will be in the 2p state (u210) at time t T, assuming that the spontaneous transition 1s transition is negligible at that time probability for the 2p

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Answer #1
  • Initially the H atom is in its ground state or s-state (n=1,l=0), written as state in the Dirac notation, .
  • An external electric field is applied, , thus behaving like a perturbation that is time dependent and we name it as (from s to p state)
  • Due to the perturbation, the atom is now in the 2p state (n=2,l=1) written as and we have to find the probabilty that it remains here at time t >> or as t

Transition coefficient, =

  

Since has no dependence within the the integral, it is evaluated as

Evaluating each of the integrals separately,

(Using the identity )

Solving the next integral,

We still have the time integral left, so let's go ahead and solve that too.

The Transmission coefficent is,

Probability =

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