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1. Ice melts at 0C° with an enthalpy of fusion = 6.01 kJ mol-1 . An...

1. Ice melts at 0C° with an enthalpy of fusion = 6.01 kJ mol-1 . An ice cube with a mass of 20.0g is placed inside an incubator at 40.0C°. Determine the total entropy change (in J/K) of this system.

2. Calculate the total entropy change (in J/K) when 50.0 g of H2 gas initially in a tank at a pressure of 145 psi is withdrawn from the tank under a constant pressure of 23.0 psi at standard room temperature. (S°,H2(g) = 130.68 J mol-1 K -1 ; recall that 1 bar = 14.5 psi)

3. Determine the free energy (in kJ/mol) for the decomposition of ammonia at 25.0 C° when the partial pressures are PN2 = 0.87 atm, PH2 = 0.25 atm and PNH3 = 12.9 atm, and ΔG°rxn = 33 kJ mol-1 .

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