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Iron thiocyanate (FeSCN2+) is a complex ion that appears orange-red in solution. Iron(III) (Fe3+) and thiocyanate...

Iron thiocyanate (FeSCN2+) is a complex ion that appears orange-red in solution. Iron(III) (Fe3+) and thiocyanate (SCN-) are both colorless in solution.

FeSCN2+ (aq) --(equilibrium)-- Fe3+ (aq) + SCN- (aq)

a) If you add Fe(NO3)3 to a solution of these ions at equilibrium, in which direction will the reaction run to reach a new equilibrium?

b) Silver ions react with thiocyanate ions to form a white precipitate. If you add silver ions to a solution of these ions at equilibrium, in which direction will the reaction run to reach a new equilibrium?

c) Hydroxide ions react with iron(III) ions to form a precipitate, Fe(OH)3. If you add sodium hydroxide to a solution of these ions at equilibrium, will the solution become darker or lighter in color?

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Answer #1

A) if we add Fe(NO3)3 to solution it will furnish Fe+3 and the reaction will move backward to reach the equilibrium.

B) if we add Ag+ ions to the solution then it will consume thicynate ions and then the concentration of these ions will decrease in the solution and reaction will move forward.

C) the solution will be lighter in colour because OH- ions will react with Fe+3 and then Fe+3 will decrease in solution and more salt is dissociated so reaction will move forward

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