Give a detailed mechanism using curly arrow notation for each of the following rxns. a. Cyclohexanone...
Give a detailed mechanism using curly arrow notation for each of the following rxns. a. Cyclohexanone with aniline b. 1,2-dimethylcyclopentane-1,2-diol with an acid catalyst c. 2-ethyl-3-methyl-1-butene with boron trifluoride: water complex as catalyst d. acetic acid with methanol and an acid catalyst e. butylacetoacetate with sodium ethoxide followed by n-hexylbromide then treatment with aqueous sodium hydroxide and heat f. 2,5-dimethyl-1,3-cyclohexanedione with lithiumdiisopropylamide the vinyl methyl ketone followed by sodium hydroxide and heat
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Give a detailed mechanism using curly arrow notation for each of
the following rxns. a. Cyclohexanone...
QUESTION 4 [1,2- versus 1,4-Addition Reactions] 4.1 Propose a detailed mechanism for the reaction of 2-butenal...
QUESTION 4 [1,2- versus 1,4-Addition Reactions] 4.1 Propose a detailed mechanism for the reaction of 2-butenal with ethynylmagnesium bromide in dry THF followed by quenching with dilute aqueous acid. (5) 4.2 Propose a plausible mechanism for the reaction of 1,3-diphenyl-2-propen-1- one with potassium cyanide in ethanol followed by aqueous work-up. 1 (5) 4.3 Predict and draw the structure of the product of the reaction of 2-methyl-1,3- cyclohexanedione with methyl vinyl ketone (3-buten-2-one) in methanol in the presence of potassium hydroxide....
QUESTION 4 [1,2- versus 1,4-Addition Reactions] 4.1 Propose a detailed mechanism for the reaction of 2-butenal with ethynylmagnesium bromide in dry THF followed by quenching with dilute aqueous acid. (5) 4.2 Propose a plausible mechanism for the reaction of 1,3-diphenyl-2-propen-1- one with potassium cyanide in ethanol followed by aqueous work-up. 1 (5) 4.3 Predict and draw the structure of the product of the reaction of 2-methyl-1,3- cyclohexanedione with methyl vinyl ketone (3-buten-2-one) in methanol in the presence of potassium hydroxide....
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