1. Predict the major products of the following reactions. (Hint: draw out Tosylate ion) ethyl tosylate + potassium tert-butoxide 2.isobutyl tosylate + NaI 3.(R)-2-hexyl tosylate + NaCN (show sterochemistry) 4.the tosylate of cyclohexylmethanol + excess NH3 5.n-butyl tosylate + sodium acetylide, H−C≡C:−Na+
1. Predict the major products of the following reactions. (Hint: draw out Tosylate ion) ethyl tosylate...
*PLEASE ANSWER THESE QUESTIONS CORRECTLY. IT'S FOR AN EXAM* *THIS WAS THE WRONG ANSWER* Predict the major products of the following reactions. (Hint draw out Tosylate ion) Part A ethyl tosylate + potassium tert-butoxide Draw the molecule on the canvas by choosing buttons from the Tools (for bonds D , H: 1200 H.C=CH2 Part B isobutyl tosylate + NaI Partc (R)-2-hexyl tosylate + NaCN (show sterochemistry)
*PLEASE ANSWER THESE QUESTIONS CORRECTLY. IT'S FOR AN EXAM* Predict the major products of the following reactions. (Hint draw out Tosylate ion) Part D the tosylate of cyclohexylmethanol + excess NH3 Part E n-butyl tosylate + sodium acetylide, H-C=C: Na
PROBLEM 6-14 Predict the major products of the following substitutions. (a) CH3CH,Br + (CH3),CO“ K+ ethyl bromide potassium tert-butoxide (b) HC=C: Nat + CH CH.CH,CH,Cl → sodium acetylide 1-chlorobutane
5. Draw the major products of the following reactions: a) (S)-2-Iodopentane + KCN in methanol. b) 2-bromo-2-methylpropane + LIN(CH(CH,),), in THF. c) 2-Chloro-1-ethanol + potassium tert-butoxide (KO'Bu). d) Cis-2-methyl-1-chlorocyclohexane + methanol. e) Potassium tert-butoxide (KO'Bu) and methyl iodide in THF. f) Draw a detailed curved arrow pushing mechanism for reaction 5d above. Draw the reactants cis-2- methyl-1-chlorocyclohexane + methanol, and show each and every electron flow that converts them into the major products.
5. Draw the major products of the following reactions: a) (S)-2-Iodopentane + KCN in methanol. b) 2-bromo-2-methylpropane + LiN(CH(CH3)2), in THF. c) 2-Chloro-1-ethanol + potassium tert-butoxide (KO-Bu). d) Cis-2-methyl-1-chlorocyclohexane + methanol. e) Potassium tert-butoxide (KO-Bu) and methyl iodide in THF. f) Draw a detailed curved arrow pushing mechanism for reaction 5d above. Draw the reactants cis-2- methyl-1-chlorocyclohexane + methanol, and show each and every electron flow that converts them into the major products.
Predict the products of the following reactions. (a) sec -butyl isopropyl ether + concd. HBr, heat (b) 2-ethoxy-2-methylpentane + concd. HBr, heat (c) di- n -butyl ether + hot concd. NaOH (d) di- n -butyl ether + Na metal (e) ethoxybenzene + concd. HI, heat (f) 1,2 @ epoxyhexane + H + , CH 3 OH (g) trans @ 2,3 @ epoxyoctane + H + , H 2 O (h) propylene oxide + methylamine (CH 3 NH 2 ) (i)...
For the following reactions, predict the MAJOR product(s). If a pair of enantiomers is expected, draw both enantiomers. NaSH Cis-1-bromo-3-methylcyclohexane acetone OTs 1. NaI/acetone 2. NaCN/DMF CH3 NaCN H,с. Br CH3 Бшн.
Question 5 Predict the major and minor products for the following reactions: NaSH НАС NaOET men major Question 6: Predict the major and minor products for the following reactions: NaOEt OTS With A - Tosylate (OTS) 0 NaOH 1 Question : Draw the plausible mechanism for each of the following transformations: CH HGC by b) HC conc. H,SO heat CH
Question : Predict the major and minor products for the following reactions: NASH -CH3 + 1 H30 HC b) NaOEt Question 6: Predict the major and minor products for the following reactions: NaOEt OTS - Tosylate (OTS) With on CHM 2210 CH3 NaOH H₂C O=O=O Question 7: Draw the plausible mechanism for each of the following transformations: CHE BECH HO HBr CH CH CH3 H₂C- conc. H,SO heat HC Insuu H Question 8 Which is the better retrosynthesis for the...
1. Predict the major products formed when benzene reacts with the following reagents. (a). tert-butyl bromide, ALCl3 (b) bromine + a nail (c) iodine + HNO3 (d) carbon monoxide, HCl, and AlCl3/CuCl (e) nitric acid + sulfuric acid. 2. Predict the major products of the following reactions. (a.) nitrobenzene + ethyl chloride/AlCl3 (b). p-methylanisole + acetyl chloride + AlCl3 (c). nitrobenzene + fuming sulfuric acid (d) benzene + CH3CH2COCl in the presence of (1) ALCl3 followed by...