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1. Predict the major products formed when benzene reacts with the following reagents.   (a). tert-butyl bromide,...

1. Predict the major products formed when benzene reacts with the following reagents.  

(a). tert-butyl bromide, ALCl3   

(b) bromine + a nail

(c) iodine + HNO3

(d) carbon monoxide, HCl, and AlCl3/CuCl   

(e) nitric acid + sulfuric acid.

2. Predict the major products of the following reactions.

(a.) nitrobenzene + ethyl chloride/AlCl3   

(b). p-methylanisole + acetyl chloride + AlCl3

(c). nitrobenzene + fuming sulfuric acid

(d) benzene + CH3CH2COCl in the presence of (1) ALCl3 followed by (2) H2O

3. Show how you would synthesize the following compounds, starting with benzene or toluene and any necessary acyclic reagents.  

(a). ethoxybenzene   

(b). para aminobenzoic acid   

(c) 2-(4-methylphenyl)butan-2-ol   

(d) benzoic acid


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Page No. Date Benzene + terk- butyl bromide ATT tert-Butylbenzene b. bromine + AlBt. + Bro Tel Aler Bromo-benzene iodine + HNPage No. Date Alch + - Nitrobenzene CH₃ CH₂-ce - Ethyl chloride - -CH CH₂ 1- Ethyl-3-nitrobenzene b. OCH₂ acetyl chloride cthca (a) o 4 al fella NaOH, H₂O 350°C Benzene Chlorobenzene HSI us Ethoxybenzene3.16) COOH HNO₃ + H₂SO4 (cone) KMnO4 alkaline NO2 P- Nitrotoluene COOH Sn/hce NH₂ p-aminobenzoic acidPage No. Date 3 (d) te CH₃C - All Benzene Toluene ACT CH 이다 NaoH 2-(4-methylphenyl) butan-2-01 COOH CH₂U Allz alkaline Kunoy

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