The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum...
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum of this compound has a broad peak between 3200 and 3550 cm-1. The 1H
NMR spectrum of A shows the following peaks: a triplet at d 0.9, a singlet at d 1.1,
one more singlet at d 1.15, and a quartet at d 1.6. The area ratio of these peaks is
3:6:1:2. The 13C NMR contains 4 signals. In the space below, propose a structure for A (1pt) and justify your claim using the data provided (6 pts)
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The mass spectrum of compound A shows molecular ion peak at m/z
88. The IR spectrum...
Compound C has molecular formula C9H10O. The mass spectrum shows a parent ion (M+) peak at...
Compound C has molecular formula C9H10O. The mass spectrum shows a parent ion (M+) peak at 134 and a base peak (largest peak) at 105 atomic mass units. The IR spectrum shows major signals at 3029, 2925, 2721, 1708, 1495, 1452, 1375, 1152, 745, and 699 cm-1. The 1H-NMR spectrum shows signals at 2.35 (singlet, 3H), 3.65 (doublet, 2H), 7.11 (doublet 2H), 7.18 (doublet, 2H), and 9.73 (triplet, 1H) ppm. The 13C-NMR spectrum shows signals at 21.1, 50.2, 128.7, 129.5,...
(c) Compound C has molecular formula C9H10O. The mass spectrum shows a parent ion (M+) peak...
(c) Compound C has molecular formula C9H10O. The mass spectrum shows a parent ion (M+) peak at 134 and a base peak (largest peak) at 105 atomic mass units. The IR spectrum shows major signals at 3029, 2925, 2721, 1708, 1495, 1452, 1375, 1152, 745, and 699 cm-1. The 1H-NMR spectrum shows signals at 2.35 (singlet, 3H), 3.65 (doublet, 2H), 7.11 (doublet 2H), 7.18 (doublet, 2H), and 9.73 (triplet, 1H) ppm. The 13C-NMR spectrum shows signals at 21.1, 50.2, 128.7,...
A compound of unknown structure gave the following spectroscopic data: Mass spectrum: M+ = 88.1 IR:...
A compound of unknown structure gave the following
spectroscopic data:
Mass spectrum: M+ = 88.1
IR: 3600cm-1
1H NMR: 1.4 (2H, quartet, J=7Hz); 1.2 (6H, singlet); 1.0 (1H,
singlet); 0.9 (3H, triplet, J=7Hz)
13C NMR: 74, 35, 27, 25
a. assuming that the compound contains C and H but may or may not
contain O, give three possible molecular formulas.
b. how many protons (H) does the compound contain?
c. what functional group(s) does the compound contain?
d. how many...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise stated, the IR data is not all inclusive, i.e. you may propose a structure which would include peaks not specifically noted but your structure must account for the peaks which are listed or which are excluded. a) Compound Q (C6H100) decolorizes Br2/CC14. IR peaks at 3500 cm- and 1640 cm"! NO absorption between 1700 and 1800 cm? b) Compound K (C6H100) does not decolorize...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT used more than once. [ Select] AC4HO2 compound has a strong IR absorption at 3300-3400 cm-1. The 1 H NMR spectrum has two singlets at 8 4.2 and 4.4 ppm: relative areas 4:2..The 13C spectrum shows 2 signals at 8 85 and 52 ppm. [ Select] AC7HO compound has a strong IR absorption at 1700 cm?, The H NMR spectrum has a singlet at...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
The following problem is similar to question 3, except the molecular formala is not provided. Yea...
The following problem is similar to question 3, except the molecular formala is not provided. Yea lecular weight of the molecule and clues from the IR to igare out the molecular formula and structur oawill have to use the tructure of the molecule 3000 2000 1500 1000 S. Propose a structure for a compound, with molecular formula CH N that fits the following spectroscopic data: IR: 3400 cm 'H NMR: 0.9 δ (triplet, 6H), 1.1 δ (singlet i H, exchanges...
A compound with the molecular formula C6H15N exhibits a singlet at d 0.9 (1H), A triplet...
A compound with the molecular formula C6H15N exhibits a
singlet at d 0.9 (1H),
A triplet at d 1.10 (3H),
A singlet at d 1.15 (9H),
& quartet at d 2.6 (2H)
In its 1HNMR spectrum. It’s Ir spectrum shows one medium
absorption band near 3400 cm^-1.
What is the structure of this compound?
NH 1
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at...
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at 8 0.9 (6H), a singlet at 8 1.1 (1H), a sextet at 01.3 (4H), a quintet at 8 1.4 (4H) and a triplet at 8 2.6 (4H) in its 'H NMR spectrum. Its IR spectrum shows a medium absorption band near 3400 cm' and its 13C NMR spectrum showed peaks at 13.7, 20.5, 30.4 and 49.2. (2 pts.) 3. Synthesize the following by showing...
A compound, C,H100, shows an IR peak at 1690 cm. Its 'H NMR spectrum has peaks...
A compound, C,H100, shows an IR peak at 1690 cm. Its 'H NMR spectrum has peaks at delta 7.9 (2H, multiplet), 7.6-7.4 (3H, multiplet), 2.95 (2H, quartet, J = 7 Hz), 1.25 (3H, triplet, J= 7 Hz). Draw its structure in the window below. . You do not have to consider stereochemistry. ChemDoodle A compound, C3H100, exhibits IR absorption at 1730 cm-1. Its carbon NMR shifts and substitution, determined by DEPT, are given below. 13C NMR: 822.6 (3), 23.6 (1),...
A compound of unknown structure gave the following
spectroscopic data:
Mass spectrum: M+ = 88.1
IR: 3600cm-1
1H NMR: 1.4 (2H, quartet, J=7Hz); 1.2 (6H, singlet); 1.0 (1H,
singlet); 0.9 (3H, triplet, J=7Hz)
13C NMR: 74, 35, 27, 25
a. assuming that the compound contains C and H but may or may not
contain O, give three possible molecular formulas.
b. how many protons (H) does the compound contain?
c. what functional group(s) does the compound contain?
d. how many...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise stated, the IR data is not all inclusive, i.e. you may propose a structure which would include peaks not specifically noted but your structure must account for the peaks which are listed or which are excluded. a) Compound Q (C6H100) decolorizes Br2/CC14. IR peaks at 3500 cm- and 1640 cm"! NO absorption between 1700 and 1800 cm? b) Compound K (C6H100) does not decolorize...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT used more than once. [ Select] AC4HO2 compound has a strong IR absorption at 3300-3400 cm-1. The 1 H NMR spectrum has two singlets at 8 4.2 and 4.4 ppm: relative areas 4:2..The 13C spectrum shows 2 signals at 8 85 and 52 ppm. [ Select] AC7HO compound has a strong IR absorption at 1700 cm?, The H NMR spectrum has a singlet at...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
The following problem is similar to question 3, except the molecular formala is not provided. Yea lecular weight of the molecule and clues from the IR to igare out the molecular formula and structur oawill have to use the tructure of the molecule 3000 2000 1500 1000 S. Propose a structure for a compound, with molecular formula CH N that fits the following spectroscopic data: IR: 3400 cm 'H NMR: 0.9 δ (triplet, 6H), 1.1 δ (singlet i H, exchanges...
A compound with the molecular formula C6H15N exhibits a
singlet at d 0.9 (1H),
A triplet at d 1.10 (3H),
A singlet at d 1.15 (9H),
& quartet at d 2.6 (2H)
In its 1HNMR spectrum. It’s Ir spectrum shows one medium
absorption band near 3400 cm^-1.
What is the structure of this compound?
NH 1
2. Draw the structure of the compound with molecular formula C H1N exhibiting a triplet at 8 0.9 (6H), a singlet at 8 1.1 (1H), a sextet at 01.3 (4H), a quintet at 8 1.4 (4H) and a triplet at 8 2.6 (4H) in its 'H NMR spectrum. Its IR spectrum shows a medium absorption band near 3400 cm' and its 13C NMR spectrum showed peaks at 13.7, 20.5, 30.4 and 49.2. (2 pts.) 3. Synthesize the following by showing...
A compound, C,H100, shows an IR peak at 1690 cm. Its 'H NMR spectrum has peaks at delta 7.9 (2H, multiplet), 7.6-7.4 (3H, multiplet), 2.95 (2H, quartet, J = 7 Hz), 1.25 (3H, triplet, J= 7 Hz). Draw its structure in the window below. . You do not have to consider stereochemistry. ChemDoodle A compound, C3H100, exhibits IR absorption at 1730 cm-1. Its carbon NMR shifts and substitution, determined by DEPT, are given below. 13C NMR: 822.6 (3), 23.6 (1),...
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