Use the following data and the van't Hoff equation lnK2K1=ΔH∘R(1T1−1T2) to estimate a value of KP...
Use the following data and the van't Hoff equation lnK2K1=ΔH∘R(1T1−1T2) to estimate a value of KP at 100 ∘C for the reaction. 2NO(g)+O2(g)⇌2NO2(g)
[Hint: First determine K at 25∘C. What is ΔrH∘ for the reaction?]
ΔfG∘[NO2(g)] = 51.31 kJ/mol
ΔfG∘[NO(g)] = 86.55 kJ/mol
ΔfG∘[O2(g)] =0
ΔfH∘[NO2(g)] = 33.18 kJ/mol
ΔfH∘[NO(g)] = 90.25 kJ/mol
ΔfH∘[O2(g)] =0
Homework Answers
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Use the following data and the van't Hoff equation
lnK2K1=ΔH∘R(1T1−1T2) to estimate a value of KP...
a) use the data given below and calculate the deltaH, delta S , delta G and...
a) use the data given below and calculate the deltaH, delta S , delta G and Kp at 25degrees celcius for the reaction 2NO(g) + O2 = 2 NO2(g) b) calculate the delta G for the reaction at 250 degrees celcius c) at what tempurature (degrees celcuis) is delta G equal to zero ? In what temperature range is this reaction product favoured? Compound NO - Delta Hf,kJ/mol =90.9 Delta S,J/mol.K =210.76 Compount O2 - Delta Hf,kJ/mol =0 Delta S,/j/mol.K=205.14...
The standard heat of formation, ΔH∘f, is defined as the enthalpy change for the formation of...
The standard heat of formation, ΔH∘f, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have ΔH∘f=0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Consider, for example, the reaction 2NO(g)+O2(g)⇌2NO2(g) with heat of formation values given by the following table: Substance ΔH∘f (kJ/mol) NO(g) 90.2 O2(g) 0 NO2(g) 33.2 Then the standard heat...
Use data from the table below to calculate the equilibrium constants at 25∘C for each reaction....
Use data from the table below to calculate the equilibrium constants at 25∘C for each reaction. Standard Thermodynamic Quantities for Selected Substances at 25∘C Substance ΔH∘f(kJ/mol) ΔG∘f(kJ/mol) S∘(J/mol⋅K) H2(g) 0 0 130.7 N2(g) 0 0 191.6 O2(g) 0 0 205.2 NO(g) 91.3 87.6 210.8 NO2(g) 33.2 51.3 240.1 CO(g) -110.5 -137.2 197.7 CO2(g) -393.5 -394.4 213.8 H2S(g) -20.6 -33.4 205.8 S2(g) 128.6 79.7 228.2 1. N2(g)+O2(g)⇌2NO(g)
3. (a) Use the data given below and calculate ∆Ho, ∆So, ∆Go, and Kp at 25°...
3. (a) Use the data given below and calculate ∆Ho, ∆So, ∆Go, and Kp at 25° C for the reaction: 4 NO (g) → 2 N2O (g) + O2 (g) (b) Calculate ∆G for the reaction at 250 °C. (c) At what temperature (°C) is ∆G equal to zero? In what temperature range is this reaction product favored? Compound ∆ Ho , kJ/mol S o , J/mol• K NO (g) 90.9 210.76 N2O (g) 82.05 219.85 O2 (g) 0 205.14
1. Thermodynamics and acid solutions a) The following reaction occurs when HCl is bubbled into water...
1. Thermodynamics and acid solutions a) The following reaction occurs when HCl is bubbled into water at 25°C and latm pressure: HCl(g) -> H+(aq) + Cl (aq) Calculate AS rxn for this reaction. b) Sketch two possible structures of the hydronium ion in water. Circle the hydronium ion in each case. Also sketch the local structures of water surrounding the hydronium and chloride ions in aqueous solution. Include the important water molecules in both sets of sketches. c) Draw a...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
please and thank you :) Part A For which of the following reactions is A Han...
please and thank you :)
Part A For which of the following reactions is A Han equal to AH of the product(s)?You do not need to look up any values to answer this question. Check all that apply. View Available Hint(s) CO(g) + O2(g) + CO2(g) C(s, graphite) + O2(8+CO(E) 0 CaCO3(g) +CaO + CO (8) Na(s) + F2(g)--NaF(s) Na(s) + F2 (1) NaF(s) 2Na(s)+F2(6)+2NaF (8) Submit Formation Reactions Part A The standard heat of formation, AH, is defined as...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction:...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction: NO(g) + O (9) NO2 (g), AG° = ? 2 03 (9) - 3 O2 (g), AG° = +489.6 kJ 02 (9) 20 (9), AGⓇ = +463.4 kJ NO(g) + O2 (9) - NO2 (g) + O2 (g), AG° = -199.5 kJ QUESTION 14 Calculate AG for the following reaction, in kJ, at 0 °C under the following non-standard conditions shown below. 2 Hgo...
I'd like the answers for 30-33 O 41.2 kJ/mol O 5.48 x10 kJ/mol O 86 kJ/mol...
I'd
like the answers for 30-33
O 41.2 kJ/mol O 5.48 x10 kJ/mol O 86 kJ/mol 48.0 kJ/mol 4.2 Question 30 (2 points) Calculate Ahº for the following reaction, using the given standard enthalpies of formation. 2NO(g) + O2(g) + 2NO2(8) AH°ANO(g)] - 90.25 kJ mol-1 AH®[NO2(g)] = 33.18 kJ mol-1 +57.07 kJ -57.07 kJ O-114.1 kJ +114.1 kJ Question 31 (2 points) The value of AH°for the following reaction is -126 kJ. Determine the amount of heat (in kJ)...
Part A) What is ΔH∘rxn for the following chemical reaction? CO2(g)+2KOH(s)→H2O(g)+K2CO3(s) You can use the following...
Part A) What is ΔH∘rxn for the following chemical reaction? CO2(g)+2KOH(s)→H2O(g)+K2CO3(s) You can use the following table of standard heats of formation (ΔH∘f) to calculate the enthalpy of the given reaction. Element/ Compound Standard Heat of Formation (kJ/mol) Element/ Compound Standard Heat of Formation (kJ/mol) H(g) 218 N(g) 473 H2(g) 0 O2(g) 0 KOH(s) −424.7 O(g) 249 CO2(g) −393.5 K2CO3(s) −1150kJ C(g) 71 H2O(g) −241.8kJ C(s) 0 HNO3(aq) −206.6 Express the standard enthalpy of reaction to three significant figures and...
1. Thermodynamics and acid solutions a) The following reaction occurs when HCl is bubbled into water at 25°C and latm pressure: HCl(g) -> H+(aq) + Cl (aq) Calculate AS rxn for this reaction. b) Sketch two possible structures of the hydronium ion in water. Circle the hydronium ion in each case. Also sketch the local structures of water surrounding the hydronium and chloride ions in aqueous solution. Include the important water molecules in both sets of sketches. c) Draw a...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
please and thank you :)
Part A For which of the following reactions is A Han equal to AH of the product(s)?You do not need to look up any values to answer this question. Check all that apply. View Available Hint(s) CO(g) + O2(g) + CO2(g) C(s, graphite) + O2(8+CO(E) 0 CaCO3(g) +CaO + CO (8) Na(s) + F2(g)--NaF(s) Na(s) + F2 (1) NaF(s) 2Na(s)+F2(6)+2NaF (8) Submit Formation Reactions Part A The standard heat of formation, AH, is defined as...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction: NO(g) + O (9) NO2 (g), AG° = ? 2 03 (9) - 3 O2 (g), AG° = +489.6 kJ 02 (9) 20 (9), AGⓇ = +463.4 kJ NO(g) + O2 (9) - NO2 (g) + O2 (g), AG° = -199.5 kJ QUESTION 14 Calculate AG for the following reaction, in kJ, at 0 °C under the following non-standard conditions shown below. 2 Hgo...
I'd
like the answers for 30-33
O 41.2 kJ/mol O 5.48 x10 kJ/mol O 86 kJ/mol 48.0 kJ/mol 4.2 Question 30 (2 points) Calculate Ahº for the following reaction, using the given standard enthalpies of formation. 2NO(g) + O2(g) + 2NO2(8) AH°ANO(g)] - 90.25 kJ mol-1 AH®[NO2(g)] = 33.18 kJ mol-1 +57.07 kJ -57.07 kJ O-114.1 kJ +114.1 kJ Question 31 (2 points) The value of AH°for the following reaction is -126 kJ. Determine the amount of heat (in kJ)...
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