Use data from the table below to calculate the equilibrium constants at 25∘C for each reaction.
Standard Thermodynamic Quantities for Selected Substances
at 25∘C
Substance | ΔH∘f(kJ/mol) | ΔG∘f(kJ/mol) | S∘(J/mol⋅K) |
H2(g) | 0 | 0 | 130.7 |
N2(g) | 0 | 0 | 191.6 |
O2(g) | 0 | 0 | 205.2 |
NO(g) | 91.3 | 87.6 | 210.8 |
NO2(g) | 33.2 | 51.3 | 240.1 |
CO(g) | -110.5 | -137.2 | 197.7 |
CO2(g) | -393.5 | -394.4 | 213.8 |
H2S(g) | -20.6 | -33.4 | 205.8 |
S2(g) | 128.6 | 79.7 | 228.2 |
1. N2(g)+O2(g)⇌2NO(g)
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Use data from the table below to calculate the equilibrium constants at 25∘C for each reaction....
Thermodynamic Data at 25 C Substance CH4 (B) (kJmol AHof 74.6 -110.5 AGof 50.5 -137.2 S (Jmol 'K) 186.3 CO (B Cl2 (g) Cu (s) 197.7 223.1 33.2 42.6 Cuo (s) 157.3 -129.7 202.8 -92.3 -273.3 285.8 241.8 -173.23 -20.6 -95.3 -275.4 -237.1 -228.6 -79.9 33.4 186.9 173.8 70.0 188.8 155.6 205.8 HF H20 (9) HNO3 (1) 91.3 33.2 81.6 45.9 87.6 51.3 103.7 -16.4 191.6 210.8 240.1 220.0 192.8 NO2 (8) NH3 02 205.2 42.6 140.9 AgNO3 (s) 124.4...
Use the data from this table of thermodynamic properties to calculate the values of ASixn for each reaction at 25 °C. 4NH,(g) + 70,(9) — 4NO2(g) + 6H2O(g) AS:n = J/mol K N,() + 0,(g) 2 NO(g) J/mol K Asian = MISU415) -1065.25 N2(9) N2H4(0) 50.6 N20(9) 81.6 N204(9) 11.1 N205(9) 13.3 NH3(9) -45.9 NH3(aq) -80.29 NH,+(aq) -133.3 NH4CI(S) -314.4 NH4NO3(s) -365.6 (NH2)2CO(s) -333.1 Na(s) Na+(aq) -240.3 Na2CO3(S) -1130.7 NaCl(s) -411.2 NaF(s) -576.6 NaBr(s) -361.1 Nal(s) -287.8 NaNO3(s) -467.9 NaOH(s)...
Use standard enthalpies of formation (in Appendix G in text) to calculate ∆H°rxn for each reaction. ∑ m∆H°f (products) - ∑n∆H°f (reactants), where m and n are coefficients. C2H4(g) + H2(g) ----- > C2H6(g) CO (g) + H2O (g) ----- > H2(g) + CO2(g) 3NO2(g) + H2O (l) ----- > 2HNO3(aq) + NO (g) 2SO2(g) + O2(g) -----------> 2SO3(g) 2C4H10 (g) + 13O2 (g) -----------> 8CO2 (g) + 10H2O (g) Substance --- ΔH° (kJ mol–) --- ΔG° (kJ mol–1) --- S°298 (J K–1 mol–1) C2H4 52.4 86.4 219.3 H2 0 0 130.7 C2H6 -84.0 -32.0 229.2 CO -110.52 -137.15 197.7 H2O -285.83 -237.1 70.0 CO2 -393.51 -394.36 213.8 NO2 33.2 51.30 240.1 NO 90.25 87.6 210.8 SO2 -296.83 -300.1 248.2 O2 0 0 205.2 SO3 -395.72 -371.06 256.76
Use data given below to calculate ΔrS∘ΔrS∘ for each of the reactions. Standard Thermodynamic Quantities for Selected Substances at 25 ∘C∘C Substance ΔrS∘ΔrS∘, JK−1mol−1JK−1mol−1 Cr(s)Cr(s) 23.8 Cr2O3Cr2O3(s)(s) 81.2 CO(g)CO(g) 197.7 CO2(g)CO2(g) 213.8 H2(g)H2(g) 130.7 H2O(g)H2O(g) 188.8 H2O(l)H2O(l) 70.0 HNO3(aq)HNO3(aq) 146.0 N2(g)N2(g) 191.6 N2O4(g)N2O4(g) 304.4 NO(g)NO(g) 210.8 NO2(g)NO2(g) 240.1 O2(g)O2(g) 205.2 SO2(g)SO2(g) 248.2 SO3(g)SO3(g) 256.8 A) 4NO2(g)+2H2O(l)+O2(g)→4HNO3(aq) B) Cr2O3Cr2O3(s)(s) +3CO(g)→2Cr(s)+3CO2(g) C) SO2(g)SO2(g) +12O2(g)→SO3(g) D) N2O4(g)+4H2(g)→N2(g)+4H2O(g)
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
no need to show work, just correct answers. please comment if need more info A voltaic cell is constructed from a standard Co2+ Co half cell (Ered - -0.280V) and a standard Ca? Cd half cell (Eºred -0.403V). The anode reaction is: The cathode reaction is: The spontaneous cell reaction is: The cell voltage is A voltaic cell is constructed from a standard Sna+Sn half cell (Ered - -0.140V) and a standard I, half cell (Ered - 0.535V). (Use the...
Thermodynamic properties of pure substances Standard thermodynamic quantities for selected substances at 25 ° C listed alphabetically by most important atom. substance Δ Hf ° (kJ/mol) Δ Gf ° (kJ/mol) S ° (J/mol∙K) Aluminum Al3+ (aq) --- -485.0 --- Al (s) 0 0 28.3 Al2O3 (s) -1675.7 -1582.3 50.9 Al(OH)3 (s) --- -1147.25 --- Bromine Br− (aq) --- -104.0 --- Br2 (l) 0 0 152.2 Br2 (g) 30.9 3.1 245.5 HBr (g) -36.3 -53.4 198.7 Calcium Ca2+ (aq) --- -553.6...
Part A Use standard free energies of formation to determine AG for this reaction at 25° C. rxn Express the free energy change to four significant figures and include the appropriate units. ? kJ AG Value rXn mol Request Answer Previous Answers Submit XIncorrect; Try Again; 5 attempts remaining You may want to reference (Page) Section 18.8 while completing this problem. G One of the reactions that occurs within a catalytic converter in the exhaust pipe of a car is...
Calculate the entropy of the following reaction, using the table below. Enter your answer without units to one decimal. 2C6H6(g) + 15O2 (g) → 12CO2 (g) + 6H2O (g) Substance ΔHf° (kJ/mol) ΔGf° (kJ/mol) S° (J/mol∙K) CH3COOH (g) -484.3 -389.9 159.8 (CH3)2O (g) -184.1 -112.6 266.4 C2H6 (g) -84.0 -32.0 229.2 C2H5OH (g) -234.8 -167.9 281.6 C6H6 (g) 82.9 129.7 269.2 CO2 (g) -393.5 -394.4 213.8 H2O (g) -241.8 -228.6 188.8 H2O (l) -285.8 -237.1 70 O2 (g) 0.0 0.0...
Use the following data to calculate the value of ΔG°rxn at 298 K for the reaction described by the given chemical equation. Include the units. Compound S°f (J/molK) DH°f (kJ/mol) CO (g) 197.7 –110.5 H2 (g) 130.7 0 CH4 (g) 186.3 –74.6 H2O (g) 188.8 –241.8 CO (g) + 3H2 (g) → CH4 (g) + H2O (g) I got -141.9 KJ/mol, but i think the units are wrong and I don't know why.