Use the following data to calculate the value of ΔG°rxn at 298 K for the reaction described by the given chemical equation. Include the units.
Compound S°f (J/molK) DH°f (kJ/mol)
CO (g) 197.7 –110.5
H2 (g) 130.7 0
CH4 (g) 186.3 –74.6
H2O (g) 188.8 –241.8
CO (g) + 3H2 (g) → CH4 (g) + H2O (g)
I got -141.9 KJ/mol, but i think the units are wrong and I don't know why.
Use the following data to calculate the value of ΔG°rxn at 298 K for the reaction...
Calculate the ΔG°rxn at 298 K using the following information. 2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l) ΔG°rxn = ? ΔH°f (kJ/mol) -207.0 91.3 33.2 -285.8 S°(J/mol∙K 146.0 210.8 240.1 70.0
Use standard enthalpies of formation (in Appendix G in text) to calculate ∆H°rxn for each reaction. ∑ m∆H°f (products) - ∑n∆H°f (reactants), where m and n are coefficients. C2H4(g) + H2(g) ----- > C2H6(g) CO (g) + H2O (g) ----- > H2(g) + CO2(g) 3NO2(g) + H2O (l) ----- > 2HNO3(aq) + NO (g) 2SO2(g) + O2(g) -----------> 2SO3(g) 2C4H10 (g) + 13O2 (g) -----------> 8CO2 (g) + 10H2O (g) Substance --- ΔH° (kJ mol–) --- ΔG° (kJ mol–1) --- S°298 (J K–1 mol–1) C2H4 52.4 86.4 219.3 H2 0 0 130.7 C2H6 -84.0 -32.0 229.2 CO -110.52 -137.15 197.7 H2O -285.83 -237.1 70.0 CO2 -393.51 -394.36 213.8 NO2 33.2 51.30 240.1 NO 90.25 87.6 210.8 SO2 -296.83 -300.1 248.2 O2 0 0 205.2 SO3 -395.72 -371.06 256.76
Use data from the table below to calculate the equilibrium constants at 25∘C for each reaction. Standard Thermodynamic Quantities for Selected Substances at 25∘C Substance ΔH∘f(kJ/mol) ΔG∘f(kJ/mol) S∘(J/mol⋅K) H2(g) 0 0 130.7 N2(g) 0 0 191.6 O2(g) 0 0 205.2 NO(g) 91.3 87.6 210.8 NO2(g) 33.2 51.3 240.1 CO(g) -110.5 -137.2 197.7 CO2(g) -393.5 -394.4 213.8 H2S(g) -20.6 -33.4 205.8 S2(g) 128.6 79.7 228.2 1. N2(g)+O2(g)⇌2NO(g)
Using values of ΔG°f, calculate ΔG°rxn for the following reaction. Is the reaction product-favored or reactant-favored? SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔG°f (kJ/mol) HgS(s) -50.6 SO2(g) -300.13 H2S(g) -33.56 H2O(ℓ) -228.59 SiCl4(g) -622.76 MgCl2(s) -591.59 ____ kJ/mol? product-favored or reactant-favored?
At 298 K, evaluate deltaG(kJ) and deltaE (V) for 2CH3OH(l) + 3O2(g) -> 4H2O(g) + 2CO2(g) S (J/mol-K) AH°y (kJ/mol) So (J/mol-K) AH(kJ/mol) Substance Substance N2(g) CH-ОН() 126.8 0 191.5 -238.6 CO(g) NH3(g) 197.9 192.5 -110.5 -46.2 CO2(g) NO(g) 213.6 +90.4 210.6 -393.5 NO2(g) +33.8 240.5 H2(g) HNO3(aq) 130.6 146.0 -206.6 H2O( 69.9 -285.8 O2(g) 188.8 H2O(g) 0 205.0 -241.8
6C02(g) + 6H2O(1)— C6H1206+602(g) Using standard thermodynamic data at 298K, calculate the free energy change when 1.92 moles of CO2(g) react at standard conditions. AGºrxn = Carbon AH°F (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 5.7 2.4 C(s, graphite) C(s, diamond) C(9) CC14 (1) 1.9 716.7 2.9 671.3 158.1 -135.4 -65.2 216.4 CCl4(9) -102.9 -60.6 309.9 CHCl3(1) -134.5 -73.7 201.7 CHCl3(9) -103.1 -70.3 295.7 CH4(9) -74.8 -50.7 186.3 CH3OH(g) -200.7 -162.0 239.8 CH3OH(1) -238.7 -166.3 126.8 H2CO(g) -116.0 219.0 HCOOH(g) -363.0...
Thermodynamic Data at 25 C Substance CH4 (B) (kJmol AHof 74.6 -110.5 AGof 50.5 -137.2 S (Jmol 'K) 186.3 CO (B Cl2 (g) Cu (s) 197.7 223.1 33.2 42.6 Cuo (s) 157.3 -129.7 202.8 -92.3 -273.3 285.8 241.8 -173.23 -20.6 -95.3 -275.4 -237.1 -228.6 -79.9 33.4 186.9 173.8 70.0 188.8 155.6 205.8 HF H20 (9) HNO3 (1) 91.3 33.2 81.6 45.9 87.6 51.3 103.7 -16.4 191.6 210.8 240.1 220.0 192.8 NO2 (8) NH3 02 205.2 42.6 140.9 AgNO3 (s) 124.4...
Methane can react with water to form carbon dioxide and hydrogen according to the following equation: CH4(g) + 2H2O(g) ↔ CO2(g) + 4H2(g) Use the following thermodynamic data at 298 K to determine the temperature at which the reaction goes from being spontaneous to nonspontaneous. Substance CH4(g) H2O(g) CO2(g) H2(g) ΔHºf (kJ/mol) -74.87 -241.8 -393.5 0 ΔGºf (kJ/mol) -50.81 -228.6 -394.4 0 Sºf (J/Kmol) 186.1 188.8 213.7 130.7
1. Use the data given to calculate the value of ΔG°rxn for the reaction at 25 °C. 2 C(graphite) + H2(g) <---> C2H2(g) C(graphite) H2(g) C2H2(g) S° (J/mol ⋅ K) 5.74 130.68 201.0 (kJ/mol) 0 0 −226.8 Report answer to four significant figures.
Calculate the ΔG°rxn using the following information. 2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l) ΔG°rxn = ? ΔG°f (kJ/mol) -110.9 87.6 51.3 -237.1