Consider the paramagnetic complex [NiCl4]2-. 1)What is the geometry of this ion complex. 2)Determine the hybridization...

Question

Question

Consider the paramagnetic complex [NiCl4]2-.

1)What is the geometry of this ion complex.

2)Determine the hybridization of Nickel.

3)Calculate the spin-only magnetic moment of this complex.

Answer 1

Answer #1

1)

The complex has tetrahedral geometry.

2)

Nickel is hybridised

The oxidation state of nickel is +2. The valence shell electronic configuration of is .

3)

There are two unpaired electrons in the complex so the number of unpaired electrons

Calculate the spin only magnetic moment

Answer 2

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