Using values of ΔHºfand Sº, calculate ΔGºrxnfor the following reaction:
NH3(g) + HNO3(aq) ®NH4NO3(aq)
Species |
ΔHºf(kJ/mol) |
Sº(J/K·mol) |
NH3 (g) |
-45.90 |
192.77 |
HNO3(aq) |
-207.36 |
146.4 |
NH4NO3(aq) |
-339.87 |
259.8 |
Using values of ΔHºfand Sº, calculate ΔGºrxnfor the following reaction: NH3(g) + HNO3(aq) ®NH4NO3(aq) Species ΔHºf(kJ/mol)...
Nitrogen Ahºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 191.6 N2(9) 0 0 N(g) 472.7 455.6 153.3 NH3(g) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 90.3 86.6 210.8 NO(9) NOCI(g) 51.7 66.1 261.8 NO2(g) 33.2 51.3 240.1 N20(9) 82.1 104.2 219.9 N204(9) 9.2 97.9 304.3 N204(0) -20.0 97.0 209.0 N205(s) -42.0 134.0 178.0 N2H4(0) 50.6 149.3 121.2 N2H3CH3 () 54.0 180.0 166.0 HNO3(aq) -207.4 -111.3 146.4 HNO3(1) -174.1 -80.7 155.6 HNO3(9) -135.1 -74.7 266.4 NH4ClO4(s) -295.0...
*** ** -305.01 -183.9 151.1 NH4NO3 (aq) -339.9 -190.6 259.8 AHºf (kJ/mol) AG°f (kJ/mol) Sº (/mol K) 0 205.1 Oxygen 02 (g) O(g) 03 (g) 249.2 231.7 161.1 142.7 163.2 238.9 Phosphorus AH° (kJ/mol) AG°f(kJ/mol) sº (/mol K) Nitrogen AH°(kJ/mol) AG°f(kJ/mol) s° /mol K) N2 (8) 0 191.6 N (g) 472.7 455.6 153.3 NH3 (g) -46.1 -16.5 192.5 NH3 (aq) -80.0 -27.0 111.0 132.0 -79.0 113.0 90.3 86.6 210.8 51.7 66.1 261.8 NH4+ (aq) NO (g) NOCI (9) NO2 (g)...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
AH = -116.4 kJ/mol 4. Consider the following reaction: NH4NO3 (s) N20 (g) + 2 H2O (g) Calculate AGº for the reaction. Substance Sº (J/mol K) NH4NO3 (s) 151 N20 (g) 220 H2O (g) 183
AH = -116.4 kJ/mol 4. Consider the following reaction: NH4NO3 (8) N20 (g) + 2 H20 (g) Calculate AGº for the reaction. Substance Sº (J/mol K) NH4NO3 (s) 151 N20 (8) 220 H2O (9) 183
Consider the following chemical reaction. NH3(g) + 2 O2(g) → HNO3(aq) + H2O(l) Calculate the change in enthalpy (ΔH) for this reaction, using Hess' law and the enthalpy changes for the reactions given below. (1a) 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(l); ΔH = −1166.0 kJ/mol (2a) 2 NO(g) + O2(g) → 2 NO2(g); ΔH = −116.2 kJ/mol (3a) 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g); ΔH = −137.3 kJ/mol
Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) N2 (g) 0 0 191.6 472.7 455.6 153.3 N(g) NH3 (g) -46.1 -16.5 192.5 NH3 (aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO (g) 90.3 86.6 210.8 NOCI (g) 51.7 66.1 261.8 NO2 (g) 33.2 51.3 240.1 N20 (g) 82.1 104.2 219.9 N204 (8) 9.2 97.9 304.3 Consider the reaction N2(9) + 202(9)—2NO2(g) Using the standard thermodynamic data in the tables linked above, calculate Grxn for this reaction at 298.15K...
Given the information below, what is AGº for the reaction: NH4NO3(s) - NH4+ (aq) + NO3(aq) AH (kJ/mol) S° (J/molk) NH4NO3(s) -365.56 151.08 NH4 (aq) -132.51 113.4 NO3(aq) -205.0 146.4 +32.3 kJ -80.7 kJ -4.34 kJ O none of these
For the reaction 2NO(g) + O2(g) ® 2NO2(g), DH° = -113.1 kJ/mol and DS° = -145.3 J/K·mol. Under which temperature conditions would the reaction be spontaneous? _________. a. For all temperatures b. Only at high temperatures c. Only at low temperatures
Using the standard entropy values: NOG), S = +210.6 J mol-1 K-1 02(0), sº = +205.0 J mol-1 K-1 NO2(g), sº = +240.5 J mol-1 K-1 calculate the standard entropy change, Asº, for the reaction: NO(g) + O2(g) NO2(g) A.-246.1 kJ B. +246.1 kJ C.-175.1 kJ D.-656.1 kJ E. -72.6 kJ