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1. Write the mechanism for the synthesis reaction for Nitration of Methyl Benzoate C₆H₅CO₂CH₃ + HONO₂...

1. Write the mechanism for the synthesis reaction for Nitration of Methyl Benzoate

C₆H₅CO₂CH₃ + HONO₂ --------> ‎C8H7NO4 H₂ O

Methylbenzoate + Nitric Acid (H₂ SO4 ) Methyl m-nitrobenzoate water

Write the complete mechanism for the reaction. Be sure to use expanded structural formulas for all chemical species. Include all bonds, non-bonding electrons, formal charges, and electron-flow arrows. DO NOT use bond-line formulas, but rather explicitly show atomic symbols. For this mechanism, show the individual resonance contributors for the arenium ion intermediate.

2. A by-product is possibly produced in this reaction if the temperature is not kept low. Write the complete mechanism for the reaction to produce the di-nitrated product. Draw each step of the mechanism on a separate line beginning on the left margin, and then explaining on the right how the reaction step occurs. Be sure to use expanded structural formulas for all chemical species. Include all bonds, non-bonding electrons, formal charges, and electron-flow arrows. DO NOT use bond-line formulas, but rather explicitly show atomic symbols. For this mechanism. show the resonance hybrid for the arenium ion intermediate.

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Ans 2.

If temperature is not kept low, possibility of formation of dinitro product increases.

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