no of moles of CH3COOH = molarity * volume in L
= 0.1*0.01 = 0.001moles
no of moles of NaOH = molarity * volume in L
= 0.220849*0.001 = 0.000220849moles
PKa = 4.75
------------ CH3COOH(aq) + NaOH(aq) -------------> CH3COONa(aq) + H2O(l)
I------------- 0.001---------------------- 0.000220849 ------------------ 0
C----------- -0.000220849 ---------- -0.000220849-------------------0.000220849
E------------ 0.000779151-------------- 0 -------------------------------0.000220849
PH = PKa + log[CH3COONa]/[CH3COOH]
= 4.75 + log0.000220849/0.000779151
= 4.75 -0.5475
= 4.2025 >>>>>answer
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