Question

The thermochemical equation for the combustion (i.e., burning) of one mole of benzene under standard conditions...

The thermochemical equation for the combustion (i.e., burning) of one mole of benzene under standard conditions is

C6H6(l)+15/2O2(g)→6CO2(g)+3H2O(l)

with ΔHocomb=–3267.7kJ/mol

  1. Is this reaction exothermic or endothermic?
  2. How much heat is released when a 5.00-g sample of benzene is burned in excess oxygen under standard conditions? (m.w. C6H6 = 78.11 u)
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Answer #1

1)

Since ΔH is negative, the reaction is exothermic

Answer: exothermic

2)

mass(C6H6)= 5.00 g

use:

number of mol of C6H6,

n = mass of C6H6/molar mass of C6H6

=(5 g)/(78.11 g/mol)

= 6.401*10^-2 mol

Now use:

Q = number of mol * ΔH

= (6.401*10^-2 mol) * (-3267.7 KJ/mol)

= -209.2 KJ

So,

209.2 KJ is heat released

Answer: 209.2 KJ

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