5. Which are constitutional isomers? A. Hexane and 3-methylpentane B. Hexane and 2,3-dimethylpentane C. Hexane and 2,3-dimethylbutane D. Hexane and cyclohexane
The five isomers of hexane are: hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane. They are constitutional isomers because they each contain exactly the same number and type of atoms, in this case, six carbons and 14 hydrogens and no other atoms. For conventional, stable, organic molecules it is necessary that each carbon atom forms four bonds to other atoms and each hydrogen atom forms only one bond. With these "rules" it is fairly straitforward to see that _all_ molecules containing just six carbons and 14 hydrogens will have the following things in common:
With this in mind, constructing all of the isomers of hexane can be accomplished by first ignoring the hydrogens and determining all the unique carbon-carbon bonding arrangements possible with six carbon
5. Which are constitutional isomers? A. Hexane and 3-methylpentane B. Hexane and 2,3-dimethylpentane C. Hexane and...
9. Which of the following is not an isomer of hexane? 1. 2,2-dimethylbutane 2. 2,2-dimethylpentane 3. 3-methylpentane 4. 2-methylpentane 5. 2,3-dimethylbutane 10. Ascorbic acid (vitamin C) is not a carboxylic acid, but rather has the structure shown below. How many stereoisomers of this compound are possible? НО. 0 ascorbic acid HO но OH a. 1 b. 3 c. 4 d. 6 II. Short Answer Questions. (70 pt total) 1. a. Identify the functional groups in the following molecule as circled....
Which of the following pairs of molecules are structural isomers? Select all that apply. 2-methylpentane and 2-methylhexane 2,3-dimethylbutane and 2-methylpentane 2-methylpentane and 3-methylpentane hexane and 2-methylhexane
INVICTUS kanes, Cycloalkanes Use the References to access important val Which of the following are constitutional isomers of cyclobutane? (Select all that apply.) 1,2-dimethylcyclobutane methylcyclopropane 1,1-dimethylcyclobutane ethylcyclopropane Which of the following are constitutional isomers of hexane? (Select all that apply.) 3-methylpentane 2,3,3-trimethylpentane 1,2-dimethylcyclobutane 2,3-dimethylbutane
CHM 211 STEREOCHEMISTRY Chapter 5 3. Hexane and 3-methylpentane are examples of: (a) Enantiomers (6) Constitutional isomers (c) Diasercomers (d) Conformers 4. Which of the following is a meso compound? CH CHE CH Htci (a) CH (b) " (d) WH+ CH.CH H- CH.CH Htc CH H 5. Which of the following is NOT true about enantiomer? (a) The have the same boiling point (b) The have the same melting poing (c) The have the same density (d) The have the...
b. Which of the following alkanes has the highest bolling point? 2,3-dimethylbutane: 2-methylpentane; 3-methylpentane; hexane c. Which of the following compounds can adopt a chair conformation in which there are no axial methyl groups? 1,1-dimethylcyclohexane; cis-1,2-dimethylcyclohexane; trans-1,2-dimethylcyclohexane; trans-1,3-di methylcyclohexane d. Which of the following compounds can adopt a chair conformation which there are no axial methyl groups? cis-1,2-dimethylcyclohexane; cis-1,3-dimethylcyclohexane; trans-1,3-dimethylcyclohexane; cis-1.4-dimethylcyclohexane cis-1,2-dimethvcyclohexane (Enter the numerical value only, without any units)? e. What is the approximate di hedral angle between the...
9. Which of the following pairs of structures represent a pair of enantiomers HyC.. HCN Had BCH H₂ CH₂ C OH H, CH.CH соон H ! CHE соон H₂C....! н HNH 10. What is the relationship of the following two compounds? COOH HCI HCI and HC COOH ні он OH a. Constitutional isomers b. Diastereomers c. Identical d. Enantiomers 11. Name the following hydrocarbon. 295 a. 2,3-dimethylbutane b. hexane c. 1,2-dimethylbutane d. 2-methylpentane
10. What is the relationship of the following two compounds? COOH HCI н CI нус and COOH HOH CH3 нон a. Constitutional isomers b. Diastereomers c. Identical d. Enantiomers 11. Name the following hydrocarbon. a. 2,3-dimethylbutane b. hexane c. 1,2-dimethylbutane d. 2-methylpentane
Order the following compounds by boiling point-lowest boiling point first (1 point) 1) Hexane 2) 2-methylpentane 3) 2,2-dimethylbutane 4) 3-bromopentane 5) 2,3-dimethylbutane 6) 1-hexanol Order 7. Justify your order for the previous question (1 point)
Which of the following can be reduced with zinc and aqueous acid to form iso-hexane? (I know the answer is A, but please explain why. Thanks!) A) 1-Bromo-2-methylpentane B) 2-Bromo-3-methylpentane C) 3-Bromo-3-methylpentane D) 1-Bromo-2,2-dimethylpentane E) 1-Bromo-3,3-dimethylpentane
Which of these is a structural isomer pair? A. heptane and 2,3-dimethylpentane B. 1,1-dichloro-2-methylpropane and 2,3-dichlorohexane C. 1,2-dichloropentene and 2,3-dibromopentene D. pentene and 2-methylbutane E. all of the above