For the cis isomer of Mo(Co)4L2 how many IR bands and Raman bands are there? For...
Hello, can you help me with any of these questions please? Any help would be much appreciated. Using diagrams indicate the symmetry elements present for each of the two isomers cis- and trans-[Mo(CO)(L)2] (IV and V). Assign the point groups of IV and V. Taking the four CO triple bonds of the carbonyl ligands (Si -S4) as your basis set, work out the reducible representation spanned by these bonds for the cis isomer V, below. IK OEC O SE Using...
Why is the trans isomer not possible for Mo(CO)4(bipy)
trans- and cis- [Co(en)2Cl2]^+ was synthesized in lab. questions are: which one is the kinetic isomer? which one is the thermodymanic isomer? what about their structure might make them that way?
How many IR and Raman peaks would be observed from the following irredeuciple representation ?
Consider the molybdenum carbonyl complex, [Mo(py)2(CO)4] (0) Draw the structures of both isomers Predict the number of CO stretching bands expected in the IR spectrum of each isomer Motivate your answer
please show how you use the character table (a) Draw the possible isomers of Ru(CO)4CI2 and determine the point group symmetry of each. Assume that the six-coordinate Ru has an octahedral-like structure. (b) How many infrared and Raman active vibrations are expected for the Co stretching motions in each isomer? (c) How many infrared and Raman active vibrations are expected for the Ru-Cl stretching motions in each isomer? (d) Can you identify the isomers of Ru (CO).Cl2 using vibrational spectroscopy?...
1. Determine the number of Infrared and Raman active bands for the following compounds. В С. A B с В (a) (b) 2. a) Build the molecular orbital energy diagram for the following molecules, O 2 ,02+ and O 2 -. b) Calculate the bond order for the three molecules, and justify which one is more stable. 3. How many unpaired electrons would you expect for the following complexes: [CoCle], [Cr(NHs)e]9 and [Cr(H2O)e3? 4. KMnO4 was expected to show no...
How many forms of a cis-isomer can be drawn? Why is this? Please explain. (the question from my homework is not asking for any specific molecule, just in general)
please help me with #1-5. thisbis inorganic chemistry 1. Determine the number of Infrared and Raman active bands for the following compounds. с в с с A в с вв (a) (b) 2. a) Build the molecular orbital energy diagram for the following molecules, O2,0 2+ and O2.. b) Calculate the bond order for the three molecules, and justify which one is more stable. 3. How many unpaired electrons would you expect for the following complexes: (CoCl] [Cr(NH).] and (Cr(H2O)...
Create an adjusted d-orbital-only MO diagram for (CO(CN)2(ox)2]3-. Do both the cis and trans versions.