(a) 5% aqueous NaOH has 5gm NaOH in 100ml of solution.
Molarity of NaOH = 5g/40g/mol ×(1000/100) = 1.25 M
M1V1 = M2V2
1.25M × 15ml = 6M × V2
V2 = 3.125ml
3.125ml of 6M HCl is required to neutralize 15ml of 5% aqueous NaOH solution . (Answer)
(b)
Solubility of NaHCO3 is not given. I have taken the standard data of 96g/L solubility at 20℃ .
Molarity of NaHCO3 =( 96g/84g/mol)/L = 1.143mol/L
M1V1 = M2V2
6M×V1 = 20ml ×1.143M
V1 = 3.81ml (answer)
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