If the pH at the half equivalence point is 4.2, what is the pKa of the acid? Half equivalence point is also called the midpoint in the text.
At half equivalence point, concentration of acid is equal to concentration of conjugate base
So,
[A-] = [HA]
Using:
pH = pKa + log [A-]/[HA]
4.2 = pKa + log (1)
4.2 = pKa + 0
pKa = 4.2
Answer: 4.2
If the pH at the half equivalence point is 4.2, what is the pKa of the...
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