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The distinction between high spin and low spin complexes disappears when you consider the lower transition...

The distinction between high spin and low spin complexes disappears when you consider the lower transition metals like rhodium, and iridium. All of these complexes are low spin, no matter what ligand is attached.

Why is this true? What does it imply about the bonding between lower transition metals and ligands?

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The distinction between low spin and high spin complex disappear in the case of lower transition metals like rhodium and iridium . This is due to the reason that the size of 4d and 5d series is exceptionally large. So the ligand easily approaches the metal and the d electrons of metal repel the incoming ligand with higher rate no matter which type of ligand is coming.

But in case of 3d series , the size of metal atom is small and hence the approach will depend on the ligand. Thats why in case of 3d series there is a distiction between high and low spin complex but not in 4d and 5d series.

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