There are 3 isomers for cis dimethylcyclohexane. Draw a structure for each isomer. Label the carbons (a, b, c...) to indicate the number of signals observed in the 13CNMR spectrum. Use the same letter for equivalent carbons.
There are 3 isomers for cis dimethylcyclohexane. Draw a structure for each isomer. Label the carbons...
2. Draw the structures of the cis-trans isomers for each compound. Label them cis and trans. If no cis-trans isomers exist, write none. a. 2,3-dimethyl-2-pentene b. 1,1-dimethyl-2-ethylcyclopropane c. 1,2-dimethylcyclohexane d. 5-methyl-2-hexene e. 1,2,3-trimethylcyclopropane
7. Draw and label both cis and trans isomers of 1-ethyl-4-methylcyclohexane. (10 pt) a. For each isomer, draw the two possible chairs and indicate which of the two will be preferred and by how much (a lot or little). (5 pt) b. Which of the four is considered the most stable (label as "best") and which is least stable ("worst")? (3 pt) c. Clearly label 1,3-diaxial interactions, if present, in any of the conformations? (2 pt) Cis Trans
5) Draw 3 isomers with the molecular formula C6H14 that do NOT contain a stereocenter Below each molecule, indicate: (i) the degrees of unsaturation (2), (ii) number of signals in the C-NMR spectrum, and (iii) number of signals in the 'H-NMR spectrum. Be sure to properly label awarded. For example you could format your answers below each structure 13 or credit will not be
1. Now construct cis-1,2-dimethylcyclohexane in the chair conformation and draw it. Perform the ring flip and draw that conformation. Which of the two conformations is preferred? This compound is meso, find the conformation that accounts for this? 2. Construct and draw trans-1-ethyl-2-methylcyclohexane in the chair conformation. Perform the ring flip and draw that conformation. Which conformation is preferred/most stable? Why? Construct and draw the cis isomer in the most stable chair conformation. Perform the ring flip and draw that conformation....
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip of both *Draw the two conformation of the cis and trans cyclohexane structures above *List the number of axial and equatorial substituents for both the cis and trans *Which isomer is more stable overall, cis or trans? Why? 2. Make a model cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane. Do a ring flip *Draw the two conformation of the cis and trans cyclohexane structures above *List the number...
For each molecule, indicate whether cis-trans isomers exist. If they do, draw the two isomers and label them as cis and trans. a. CH3 - CH2 -CH=CH, b. CH3-CH2-CH=CH c. 2-Pentene d. 1,2-Dichloroethene
In each of the cases below, which isomer is more stable? a) 1,4-dimethylcyclohexane (cis/trans?): b) 1-bromo-2-methylcyclohexane : (cis/trans?) c) 1,3-diethylcyclohexane (cis/trans?)
5. State the number of isomers that exists for the following complexes, name each type of isomer and draw the structure of the isomers: (8 points) Number of possible isomers Structure of each type and Name a. [Co(NHa)4Fl b. [Fe(H20)2Cla] c. [Pt(NHs)2Cl2] d. [Fe(CO)s(NH3)3]3
5. State the number of isomers that exists for the following complexes, name each type of isomer and draw the structure of the isomers: (8 points) Number of possible isomers Structure of each type and Name...
Draw the structure for the isomer of the molecular formula C3H6O
next their spectra, label their unique protons, then assign each
signal to the proton or group of protons they represent.
3) Draw the structure for the isomer of the molecular formula C3H6O next their spectra, label their unique protons, then assign each signal to the proton or group of protons they represent. a. 10 8 7 2 1 0 b. 10 8 6 1 t C. 10 0
how many isomers and the point group of each isomer
MX -1. How many isomers? 3 isomer 2. point groups ? - EV cis-102N