Cyaphide” ([C≡P]-) is the phosphorus analog of the cyanide ion
A). supposing that cyaphide and cyanide are found in similar positions in the spectrochemical series, draw the structure of hexa(cyaphide)iron(III) anion, noting any overall charge
.(b) Draw its crystal field splitting diagram and show its occupation by d-electrons
.(c)Predict the spin-only magnetic moment
Cyaphide” ([C≡P]-) is the phosphorus analog of the cyanide ion A). supposing that cyaphide and cyanide...
1. What distinguish a transition metal from a main group metal? 2. Why is zinc not considered a transition metal? 3. Write the electronic configuration of the following ions; V". Cr, Mn, Fe, Ni, Ti" 4. What are basic assumptions of Crystal Field Theory? 5. Compounds containing the Scion are colorless whereas those containing Ti* ion are colored. Explain. 6. Predict the number of unpaired electrons in [Cr(en) ions. 7. What are spectrochemical series? 8. The compound hexaminecobalt(III) chloride is...
Q1. The following species a)-c) all contain complex ions of transition metals, which you can assume take up an octahedral geometry. a) [RuCl3(H2O)3] b) [Ir(bpy)3]Cl3 ; bipy = 2,2'-bipyridine c) K2[Mo(NCS)6] For each species: i) draw all the possible isomers of the complex ions; ii) calculate the charge of the metal, and the dn configuration; iii) draw a diagram showing d orbital occupancy and, where high and low spin cases are possible, predict which will be favoured considering the spectrochemical...
5. What was the purpose of the NaNO3 solution in this experiment? 6. Could a solution of NaCl be used instead of NaNO3? 7. What was the purpose of FeSO4 solution in this experiment? 8. Could a solution of FeCl, be used instead of FeSO4? 9. Could a solution of NaSO4 be used instead of FeSO4? 10. Calculate the standard cell potential for the spontaneous redox reaction between a Pb(s)/Pb(NO3)2(aq) half-cell and a Ag(s)/AgNO3(aq) half-cell. Which metal would be oxidized?...