LiF has a Schottky formation energy of 2.6 eV and a bandgap of 12 eV. At 500 C, estimate the relative concentrations of ionic and electronic defects and determine which are dominant on an absolute concentration basis.
To solve this problem, the conductivities of the electrons, holes and ions have to
be calculated.
i) For the concentration of electrons :
For the concentration of ionic
Now ionic concentration is more dominant at 500 °C.
LiF has a Schottky formation energy of 2.6 eV and a bandgap of 12 eV. At...
LiF has a Schottky formation energy of 2.6 eV and a bandgap of 12 eV. At 500 °C, estimate the relative concentrations of ionic and electronic defects and determine which are dominant on an absolute concentration basis.
Calculate the number of Schottky defects per cubic meter in NaCl at 500°C. The energy required to form each Schottky defect is 2.6 eV. T 500 22t 3B.
Calculate the number of Schottky defects per cubic meter in NaCl at 500°C. The energy required to form each Schottky defect is 2.6 eV. T 500 22t 3B.
A Silicon semiconductor has its Fermi energy at 10kT below the center of the bandgap. Assume T = 300K, 10 3 1.5 10 i n x cm − = , kT = 0.026eV, Eg = 1.12eV. a) (5 points) Is the semiconductor n type or p type and why? b) (10 points) Determine 0 0 n and p and impurity density and type (assume there is only one type of impurity) c) (10 points) What type and concentration of impurities...
Please show work for problems 1-4
1. Calculate the activation energy for vacancy formation in aluminum, given that the equilibrium number of vacancies at 500°C (773 K) is 7.57 x10m3. The atomic weight and density (at 500°c) for aluminum are 26.98 g/mol and 2.62 g/cm, respectively 2. What point defects are possible for Al,0, as an impurity in Mgo? How many Al ions must be added to form each of these defects? 3. A sheet of steel 4.5 mm thick...
Need help solving this questions.
In problems 1-3, Assume n- 100 cm, E1 eV, 1000 cm-/V.s, g.-12, s,-8.85% 10-14 Fern, and KT4-26-my 250 cma/V.s, Problem 1 A silicon sampl equilibrium has electron concentration given asn -e0'x+2305, where x is distance. Determine the (a) position of the Fermi level with respect to the conduction band, Ee, at x-1-um, (b) electron diffusion current density at x-1- m, and (c) sample conductivity at x-0 Problem 2 Consider a silicon PN-junction with acceptor and...
Problem 3 Part A The energy levels of atomic mattinium are given by the expression -10.2 eV En = ηλ/2 (a) Draw an energy level diagram showing the lowest four energy levels of atomic mattinium, as well as the ionisation limit. Label each of the energy levels with their quantum number and their energy in electron volts. (b) One of the puzzles of classical physics was that the absorption and emission spectra of atomic gases were different from one another....
7. Saha-Langmuir Equation for Hydrogen: A reaction of great relevance in astrophysics is the ion- ization/recombination of atomic hydrogen: Hp+ +e-, which can be treated like other chemical reactions -or equivalently, in effect as the adsorption of an electron onto a proton Assume: (i) thermodynamic equilibrium conditions prevail; and that (ii) all species can be treated as ideal gases (meaning the particles are sufficiently dilute so that Coulombic interactions amongst the free charged species can be neglected); (iii) the system...
was CHE 301 11/15/12 Another sample of KMnO4 solution has 80% of light of a givenpassing through it transmitted when a cell of 1 cm was used for the sample analysis and the molar absorptivity was 2.0 LMol'cm'. The cell length is 1 em not 4 cm as stated previously. (a) Determine the unit of the molar absorptivity (core ora) (b) The concentration"e" of the KMnO, sample in 1 molL and (ii) gl. 2. The wavelength of green light is...
Can't figure out the concentration of the complex of
solns. 10, 11, 12, 13, & 14.
Modern Experimental Chemistry Chemistry 153 The Iron(III) Thiocyanate Complex Purpose of the Experiment To determine the chemical formula of a complex ion and measure its formation equilibrium constant Equipment Spectro Vis spectrophotometer and LabQuest, cuvette, 25-mL buret (3), ring stand, buret clamp (2), 50-mL beaker (3), small plastic beakers Reagents SCN, as KSCN, 0.00200 M solution Fe; as Fe(NO), 0.00200 M solution and a...
The reaction can be speeded up by using a catalyst that reduces the activation energy. The most popular catalysts are based on iron (Fe) and ruthenium (Ru). The table shows the variation in the concentration of Nz(g) as a function of time for a reaction carried out at 500 °C and 200 atm in the presence 0 0.1 0.2 0.3 0.4 0.5 0.6 of an Fe catalyst:. IN,(e)] (mol/L) 2.00 1.68 1.42 1.19 1.01 0.846 0.710 7. Use these data...