Does an activating group or a deactivating group have stronger directing effects on a benzene ring?
An activating group (electron releasing/donating) has stronger directing effects on a benzene ring because its presence on the benzene ring makes the benzene ring more reactive towards the electrophilic substitution reaction and increases the rate of reaction whereas a deactivating group (electron withdrawing) slows down the reaction of the benzene. The effect of activating group is as shown which makes the benzene ring Ortho/para directing
The effect of the deactivating group is as shown which makes the benzene ring meta directing towards electrophilic substitution
Does an activating group or a deactivating group have stronger directing effects on a benzene ring?
The carboxymethyl group is directing and HNO3 H2SO4 meta; deactivating meta; activating para; activating • ortho; deactivating
An acyl group is Strongly deactivating and it is meta and it is meta directing strongly deactivating weakly activating The ring with C NisTmoderately activating ▼ and it is ortho-para ▼ directi n strongly deactivating moderately deactivating ortho-para meta para moderately activating
An NH2 substituent in an aromatic ring is: Select one: a. activating ortho-, meta- and para-directing b. deactivating and ortho- and para-directing c. deactivating and meta-directing d. activating and meta-directing e. activating and ortho- and para-directing
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring ?deactivating اختر أحد الخيارات CI- CO2H- NO - O NH2- OH-
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? Select one: -CIN 0 -NH₂ O NO₂ O-CO₂H
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? of Select one: O -NH2 O-SO3H O-1 0 -CN O-OCH3
10. (12 points) Cua CHaCHa Les eb Predict whether the following substituents on the benzene ring are likely to be ortho/para directing or meta directing and whether they are likely to be ring activating or ring deactivating ..n(CH3)2 CEN ОСН з -NO C-OCH 11. (6 points) Starting with benzene as the only aromatic starting material, devise a
Assume the functional groups below are attached to a benzene ring. Circle the functional groups that are activating. Put a triangle around those that are deactivating. Predict the directing effect of each group (either o,p or m). Do you see any trends? {-Br 4-CF3 OCH3 {NH2 & NH3 NO2 &-coh 10
The N,N,N-trimethylammonium group, -N(CH3)3*, is one of the few substituents on a benzene ring that is a deactivating, meta-directing group, yet has no electron-withdrawing resonance effect. Explain.
Label the following as activating (A) or deactivating (D), and then also as ortho/para directors (OP) or meta directors (M). Write the answer below each group. N "Here with other ty A/D? = = = = OP/M? = f) Using resonance structures, explain why a nitro group is "meta-directing" (i.e. does the nitro group actually affect the meta positions?) g) As mentioned in class, the halogens are a bit anomalous as substituents on the aromatic ring: they are deactivating groups,...