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Why is it that HClO is a stronger acid than HBrO, when HBr is a stronger...

Why is it that HClO is a stronger acid than HBrO, when HBr is a stronger acid than HCl? I thought that more electronegative atoms created stronger bonds with hydrogen and so therefore made it more difficult for those acids to dissociate.

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Answer #1

This is because of the fact that chlorine is more electronegative than bromine. The electronegativity difference of Cl and O is less than that in the case of Br and O. So, the BrO bond is more polar. And hence, the H-BrO bond is stronger than H-ClO. Also, the resulting negative charge on the conjugate base ClO- is more stable than on the base BrO- due to the high electronegativity of chlorine. As a result, HClO is a stronger acid.

HCl bond is stronger than HBr bond. So, the former requires more energy to dissociate and hence dissociates less.

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