Question

Consider the titration pf 25.00 mL of 0.100 M weak acid HA whose Ka = 6.80...

Consider the titration pf 25.00 mL of 0.100 M weak acid HA whose Ka = 6.80 X 10-5 with 0.100 M NaOH. Calculate the fractional composition for both HA and A- and the pH at the following titratant volumes in mL.

1, 3, 5, 10, 12, 13, 15, 20, 21, 22, 26, 24

Plot both fractional compositions vs. pH using a scatter plot with a smooth curve through the points.

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Answer #1

Volume of NaOH added(ml)

Composition(NaOH/HA)

PH

1

0.04

2.78

3

0.12

3.30

5

0.2

3.56

10

0.4

3.99

12

0.48

4.13

13

0.52

4.17

15

0.6

4.34

20

0.8

4.76

21

0.84

4.88

22

0.88

5.03

24

0.96

5.54

26

1.04

11.29

I didn’t get composition of A- and HA, I simply take NaOH/HA (vol/vol) which will be equal to A- / HA upto 24ml and after that for 26 ml it will be equal to 1.

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