For each of the following, determine the point group of the species
9. [ZnCl3Br]2– (VSEPR = tetrahedral)
10. Au(porphyin)(OH2)2
For each of the following, determine the point group of the species 9. [ZnCl3Br]2– (VSEPR =...
For each of the following, determine the point group of the species. 5. [Ni(en)3]2– (Λ) 6. Cr(OH2)3(OH)3 (mer) 7. Fe(CO)5 8. Zr(C6H6)2 (eclipsed)
10.) Specify the electron-domain geometry for the following two species using the VSEPR model: XeCl4 and IO4−. For each species, predict the bond angles based on the electron-domain geometry. (a) XeCl4 geometry: linear trigonal planar bent tetrahedral trigonal pyramidal trigonal bipyramidal seesaw T-shaped octahedral square pyramidal square planar pentagonal bipyramidal pentagonal pyramidal pentagonal planar bond angle: 60° 72° 90° 109.5° 120° 180° (b) IO4− geometry: linear trigonal planar bent tetrahedral trigonal pyramidal trigonal bipyramidal seesaw T-shaped octahedral square pyramidal square...
Specify the electron-domain geometry for the following two species using the VSEPR model: KrCl4 and BrO4. For each species, predict the bond angles based on the electron-domain geometry. (a) KrCl4 geometry linear trigonal planar bent tetrahedral trigonal pyramidal trigonal bipyramidal T-shaped octahedral square pyramidal square planar pentagonal bipyramidal pentagonal pyramidal pentagonal planar bond angle: 72° 109.5° 120 180° (b) Br04 geometry: inear trigonal planar bent tetrahedral trigonal pyramidal trigonal bipyramidal seesaW T-shaped octahedral square pyramidal square planar pentagonal bipyramidal pentagonal...
For each of the following, determine the FOS(Formal oxidation state) and dn configuration for the transition metals. Be sure to clearly show the FOS and/ or charges for all relevant ligands and species. A) Zr(C6H6)2 B) [Zn(OH2)4][ZnCl4] C) TpMoO(OMe)2 (Tp = tris(pyrazol-1-yl)borate; see Fig. 4.2 of Jones) D) .Au(porphyin)(OH2)2 E) (CpW(CO)3)2 (contains a W–W bond)
All parts please!!
1. Determine the point group for each of the following molecules. If the molecule has a C,axis, draw and label the axis on the molecular structure. Similarly, draw all mirror planes that are present in the molecule. Feel free to draw multiple copies of a molecule to show the symmetry elements more clearly. NH3 b) Br NH / 111111 -Cr F- Cr. OH OH2 ço e) Çih f) CO IZ ОН CO g) F.
Long Answer: Answer each question completely 9. (14 Points each) For each of the following species: a. Draw the correct three dimensional structure b. Give the base shape and molecule shape c. Assign the appropriate point group d. Perform a complete vibrational analysis including the representations for translational, rotational and vibrational modes e. For the vibrational modes, determine which are IR active and which are Raman active SeF4
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Academic Year 2019-20 Chem 06.100: Molecular Geometry and VSEPR Theory Species & No. Valence Lewis Structure Electron Domain Geometry Molecular Geometry Perspective (30) Drawing w/labeled Bond Angles Molecular Shape Designation AXE. Formal Charge on Each Atom Polar or Non-polar? н CHA Trigonal Pyramidal Tetrahedral 109.5 AX: H-C-H H CO H=0 Non-polar 8 NH) Trigonal Tetrahedral Pyramidal 100 HO TH-N-H Ах, Polar O Trigonal Planar NO, Trigonal Planar :-1 0=0 AX, E, I 1 non polar -...
Determine the molecular point group for each of the following ions or molecules: 1) ClF3, 2) IF5, 3) I3-, 4)XeO4, 5)XeOF4, 6)XeF4, 6) SF2
DRAW NEATLY the shapes, and determine the POINT GROUPS, for each of the following SIMPLE SPECIES (11) [PO4] 3– (12) [PCl4] + (13) [PCl6] - (14) [BrF4] - (15) BrF5 (16) [lF6] + (17) lF7 (18) [NO3] - (17) [NO2] - (18) [SO3] 2- (19) [ClO3] - (20) [NO2] -
Determine the Bravais lattice and point group for each of the following materials: Si (space group: Fd-3m), Anatase TiO2 (space group: I41/amd) LiCoO2 (space group: R-3m) LiFePO4 (space group: Pnma)