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1- Arrange the species N2+, N2, N2-, N22-, in order of increasing bond length (justify your...

1- Arrange the species N2+, N2, N2-, N22-, in order of increasing bond length (justify your ordering based on MO Theory and any other explanation you can come up with).

2- For each of the species specify which molecular orbital is the HOMO and which is the LUMO.

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Answer #1

Electronic configuration of  is, 1s2, 2s2, 2p3.

Molecular orbital diagram of N2+ is given bellow.

Here Homo is orbital and LUMO is orbital.

Molecular orbital diagram of N2 is given bellow.

Here HOMO is orbital and LUMO is orbital.

Molecular orbital diagram of N2- is given bellow. Here HOMO is orbital and LUMO is orbital.

Molecular orbital diagram of N2 2- is given bellow.

Here HOMO is orbital and LUMO is orbital.

As we know bond length is inversely proportional to bond order thus, bond lenght order is

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