Discuss the characteristics (1) Kinetics (2) Stereochemistry and (3) Rearrangements for (a) the SN1 mechanism and...
1.) Determine the mechanism. (Sn1 or Sn2) 2.) Show step by step reaction mechanism of nucleophilic substitution including transition states 3.) Draw the products, including stereochemistry Br + CN acetone
1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH3 CI + NaOCH2CH3 2. Draw complete mechanism with arrows for the SN1/E1 mechanism. Check for carbocation rearrangements. Hac CH + H2O
Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. Nato=CH₂ E2 ran Br major 2. Draw complete mechanism with arrows for the SN1/E1 mechanism. Check for carbocation rearrangements. CH3 SMI 애 + H₂O7
Consider the following statement regarding Sn1, Sn2, E1, E2 reactions. To which mechanism(s), if any, apply? 1.Rearrangements of the carbon skeleton are possible?
Explain the effect of the solvent on the reaction kinetics with respect to an SN1 mechanism? - solvent used was 60/40 acetone/water solution up to 100ml
9. a) Write the detailed Sn1 mechanism for the reaction of (S)-3-bromo-3-methylhexane with H20, showing curved arrows, relevant lone pairs, formal charges, stereochemistry for each step. Include any transition states and/or intermediates, and name the product(s). b) A racemic mixture results from a reaction of the chiral alkylbromide starting material below, and acetate. at hope ܬ Write the complete mechanism for the synthesis. Show the curly arrows, relevant lone pairs and all formal charges for each step. Include any transition...
Explain the effect of the solvent on the reaction kinetics with respect to an SN1 mechanism. How to explain 50%/50% acetone/water & 60%/40% acetone/water with reference to the above to the above (from results half life was way less in 50/50) According to the data chart, the Rate constant for the hydrolysis of tertbutylchloride in 50/50 acetone/water (volume) is: k=1.03E-2/min^1 The rate constant for the hydrolysis of tertbutylchloride in 60/40 acetone/water is: K=2.9E-3/min^-1
1-provide an sn1 mechanism between AgNO3 and bromobenzene? 2-provide an sn2 mechanism between AgNO3 and bromobenzene?
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. mer 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. H3C CI CH OH CH2CH3 општироотип солио 3. Provide the product/s for the following reactions. Indicate if the reactions proceed via an SN1, or SN2 mechanism. Indicate proper stereochemistry if it is applicable. Show the mechanisms NaCN...
Thermodynamics and kinetics of SN1, SN2, E1, and E2 mechanisms. 2. Draw the reaction coordinate diagrams of the following reactions according to the type of mechanisms given and include the following: a) Label the reactant, product, intermediates, and a drawing of the transition state of the rate determining step. If there are multiple E, label the largest E (5 pts) b) State if AG rx is <0 or >0 and make sure your diagram reflects the AGxn. (4 pts) Hint:...