Detailed mechanism for 3,3-dimethylpentan-2-ol heated with sulfuric acid to produce a major product of 2,3-dimethylpent-2-ene
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Detailed mechanism for 3,3-dimethylpentan-2-ol heated with sulfuric acid to produce a major product of 2,3-dimethylpent-2-ene
(R)-3,3-dimethylpentan-2-ol is heated with concentrated sulfuric acid Select all products that are formed.2,3-dimethylpent-2-ene(Z)-3,4-dimethylpent-2-ene3,3-dimethylpent-1-ene(E)-3,4-dimethylpent-2-ene3,3-dimethyl-pent-2-ene(S)-3,3-dimethylbutane-2-thiol
(major product) PROBLEM 8-5 ose a mechanism to show how 3,3-dimethylbut-1-ene reacts with dilute aqueous H2SO4 to give 2,3-dimethylbutan-2-ol and a small amount of 2,3-dimethylbut-2-ene.
1. Which alkene is the least stable? A 2,4-dimethylpent-2-ene B 2,4-dimethylrent-1-ene C 2.3 dimethylent-2-ene D. 3,4-dimethylpent-2-ene E. 3,4-dimethylpent-1-ene A. Solventio B. Hydrogen C. Heat Cap D. Both A a E Both Ba 8. Why is 2. Which is the major product from reaction of sodium iodine with (R)-2-bromo-3-methylbutane in dicholormethane (methylene chloride? A. 2-iodo-2-methylbutane B. 2-methylbut-2-ene C. (S)-2-iodo-3-methyl butante D. 2-methylbut-l-ene E. No Reaction A Atom B. Reso C. Hyb D. Pols E. Indi 3. Which is the major product...
4. Predict the eliminations products formed (E-1 mechanism) when(S)-4-ethyl-4- methylhexan-3-ol is heated with concentrated sulfuric acid. Also, identify the rate determining step and the major product using Zaitsev's Rule? (Mechanism must be shown to receive full points). (15 pts) CH3 HaC con. aq. H2SO heat он CH3
2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol. Show a mechanism for this reaction. 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain.
2. Acid-catalyzed hydration of 3,3-dimethyl-1-butene produces 2,3-dimethyl-2-butanol Show a mechanism for this reaction. 3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol
Complete the electron-pushing mechanism for the E1 reaction when 2-methylbutan-2-ol is treated with 20% sulfuric acid. Hint: The E1 mechanism involves dissociation of the hydroxyl group from the substrate. The acid is used to convert the hydroxyl group to a good leaving group. Do not delete any pre-drawn bonds/charges/lone pairs. Complete the electron-pushing mechanism for the E1 reaction when 2-methylbutan-2-ol is treated with 20% sulfuric acid Map a) Use two curved arrows to show the fast b) Use a curved...
Complete the electron-pushing mechanism for the E1 reaction when 2-methylbutan-2-ol is treated with 20% sulfuric acid. Use two curved arrows to show the fast protonation of the alcohol. Use a curved arrow to show the dissociation of the leaving group from the substrate. Draw the organic product of the E1 dehydration Use two curved arrow to show the deprotonation of the carbocation intermediate.
major product of the reaction? 1. excess 12 & NaOH 2. H30* Product O 3,3-dimethylbutanoic acid 2,2-dimethylpropanoic acid 1-iodo-3,3-dimethyl-2-butanone 3-iodo-3-methyl-2-butanone
What is Zaitsev’s rule? Give the mechanism for the acid-catalyzed E1 reaction of 2-butanol. Give the mechanism for the base-catalyzed E2 reaction of 2-bromobutane. Draw all possible products. You expect three products from the elimination reaction 2-butanol. What are they? The E2 mechanism is a one-step mechanism. True or False? Explain. Which of these two alcohols would you expect to be more reactive under H3PO4/aqueous conditions? Why? Give the structure of the main product in both cases. 1-phenyl-1-propanol 1 -cyclohexyl-1-propanol...