A sample of argon gas has a volume of 735 mL at a pressure of 1.20 atm and a temperature of 112 ∘C. What is the final volume of the gas, in milliliters, when the pressure and temperature of the gas sample are changed to the following, if the amount of gas does not change?
1) 669 mmHg and 280 K
2) 0.58 atm and 75 ∘C
3) 14.9 atm and -15 ∘C
1)
volume V1 = 735 mL
pressure P1 = 1.20 atm
temperature T1 = 112 oC = 385 K
P2 = 669 mmHg = 0.88 atm
T2 = 280 K
P1 V1 / T1 = P2 V2 / T2
1.20 x 735 / 385 = 0.88 x V2 / 280
V2 = 729
final volume = 729 mL
2)
P2 = 0.58 atm
T2 = 75 oC = 348 K
P1 V1 / T1 = P2 V2 / T2
1.20 x 735 / 385 = 0.58 x V2 / 348
V2 = 1374
final volume = 1374 mL
3)
P2 = 14.9 atm
T2 = -15 oC = 258 K
P1 V1 / T1 = P2 V2 / T2
1.20 x 735 / 385 = 14.9 x V2 / 258
V2 = 39.7
volume = 39.7 mL
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