For each of the following complexes, give an energy level diagram of the split d orbitals, fill the orbitals with electrons appropriately, and indicate the number of unpaired electrons (spins). In addition, calculate the LFSE for (a)–(f).
(a) [Co(NH3)4(CN)2] (b) [Cr(CN)6]3– (c) [FeF6]3– (d) MnO4– (tetrahedral) (e) [Cu(H2O)6]2+ (f) [Cd(CN)4]2– (g) [Ni(CN)4]2
For each of the following complexes, give an energy level diagram of the split d orbitals,...
Determine the number of unpaired electrons, magnetic moment, and LFSE for following complexes: f. MnO4− g. Cu(H2O)6]2+
(b) Determine the oxidation state of the metal, the d electron configuration, the number of unpaired electrons and the ligand field stabilisation energy for the following complexes: (i) [Co(NH3)5Br]2+ (ii) [MnO4]- (iii) [Fe(CN)6]3- (iv) [Cu(H2O)6]2+
1. Consider the following 4-coordinate complexes. For each of these: a. Do you expect the complex to be tetrahedral or square planar? Why? b. Draw an electron-orbital occupancy diagram for the d orbitals. c. If the complex is tetrahedral, calculate an LFSE in units of 4. Note that, for tetrahedral complexes, e orbitals are -3/54 relative to the average d-orbital energy, and t, orbitals are +2/54 relative to the average d-orbital energy. Ni(CO). [Rh(PPh.) (CO), [Rec] [PdCl.Bry] 2. Which of...
How do the d orbitals split in each of the following complexes? (a) [Ni(CN)s]s with Dan Symmetry (c) [PtCla]2 with Dan Symmetry (b) [Ni(CN)s (d) [CuBra] with Td symmetry with Cay Symmetry
Which of the following complexes has the largest crystal field splitting of the d orbitals? A. [Fe(H2O)6]3+ B. [FeF6]3– C. [Fe(NH3)6]3+ D. [FeI6]3– E. [Fe(CO)6]3+
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
Inorganic Chemistry
Please help me with #5-#7
5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) Fe(CN) b)[Fe(H2O) c) [CoCl2 (tetrahedral) 6. Of the two complexes (a) [CoFeP and (b) [Co(en) one appears yellow and the other appears blue. Match the complex to the color and explain your choice. 7. Three different solutions with orange, green, and violet colors were prepared. Associate each color to the following complexes: [CrCle, (Cr(NHs, and (Cr(H2O
All of the following complexes are either octahedral or tetrahedral. Determine if the complex is diamagnetic or paramagnetic, if the complex is high spin or low spin, and ii) the number of unpaired electrons. Unpaired Electrons Spin low Magnetism Complex [Fe(CN)6]* [Co(NH3)4]3 13+ 14- 4+ [Ru(CO)6]
All of the following complexes are either octahedral or tetrahedral. Determine if the complex is diamagnetic or paramagnetic, if the complex is high spin or low spin, and ii) the number of unpaired electrons....
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
inorganic chem
please help with #3-#5
3. a) Build the molecular orbital energy diagram for the following molecules, O2, O2 and 02. b) Calculate the bond order for the three molecules, and justify which one is more stable. 4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]. b) (Pt(NH3).Cis)" c) [Mn(CN):)" d) (Coen)(PPha)]PO4 e) [Ni(bipy))(NO3)2. 5. Give chemical formulas for the following coordination complexes a) Triammineaquadichlorocobalt(III) chloride b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato)iron(lll). d) Tri--carbonylbistricarbonyliron(0)). e) /-oxo-bis(pentaamminechromium(III)). 5. Draw...