Question

Draw one product structure for the following Diels–Alder reaction. For ONLY the chirality...

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Draw one product structure for the following Diels–Alder reaction. For ONLY the chirality centers with D and C(=O)H groups, specify the stereochemistry via wedge-and-dash bonds. (D is deuterium, an isotope of hydrogen. Include it in your drawing by either double clicking on an atom and typing \"d\" or by choosing D in the bottom row of the atoms menu.)

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Answer #2
Concepts and reason

Diels – alder reaction is [4 + 2] cycloaddition reaction between conjugated diene and dienophile (substituted alkene or alkyne) to form substituted cyclohexene. This reaction undergoes in a single step with no intermediates in this reaction.

Fundamentals

A compound with conjugated double bond in a system is represented as diene.

Diene

A substituted alkene or alkyne is represented as dienophile.

H
Н.
н
Н
Dienophiles
I
I

Example:

+

According to stereochemistry,

Cis reactants lead to Cis product and trans reactants leads to trans products.

H
H
H
Transition state
O:

-н
ID
н
H
Transition state

Ans:

H
и
H
A
+
.н
D
шс
D
H
O:

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