(20pts)Assume H2S is a linear molecule. The orbital energies of H and S, as well as the character...
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귀 #g)Consider the hypothetical hexagonal planar molecule SH which has D "symmetry. (4 pt) Determine the symmetries and degeneracies of the valence s and p orbitals on the central sulfur atom. a. 3s 3py 3px 3p: Symmetry labels t Draw the symmetry adapted orbital combination formed by the six terminal H atoms. Aid
Draw a molecular-orbital diagram for LiH and write the
electronic configuration.
Indicate the relative energies of the Li 2s and H 1s atomic
orbitals by reference to the VOIE values in Table 4-4.
The first ionization energy of LiH has not been measured, but
calculation predicts it to be about 8 eV.
To support this value, which atom in LiH must have a partial
negative charge?
(table 4-4 in pic)
10. Draw a molecular-orbital diagram for LiH and write the...
Draw a molecular-orbital diagram for LiH and write the
electronic configuration.
Indicate the relative energies of the Li 2s and H 1s atomic
orbitals by reference to the VOIE values in Table 4-4.
The first ionization energy of LiH has not been measured, but
calculation predicts it to be about 8 eV.
To support this value, which atom in LiH must have a partial
negative charge?
(table 4-4 in pic)
10. Draw a molecular-orbital diagram for LiH and write the...
1) The orbital potential energies for the 4s and 4p of Br are -18.65 ev and -12.49ev, respectively. Recall that the H 1s is -13.61ev. The MO diagram for HBr is not exactly the same as HF. Draw the MO diagram for HBr, including energy levels, each orbitals shape, each orbitals character (meaning what atomic orbitals contribute to each M.O. and how much), symmetry labels (e.g. and , * and *), indicate the HOMO and LUMO, the bond order...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital ionization potentials: H(1s) - 13.6 eV, C(2s) -19.5 eV, C(2p) -10.7 ev. (6C, 11) E x +y?,z? 1 1 1 203 3C on 1 1 1 1 1 1 1 T - 1 0 2 1 1 -1 | 1 -1 1 -1 -1 TOT- 2 25; 1 1 - 1 1 -1 1 -1 1 30, 1 1 1 -1 0 1 -1...
11. The molecule methane, representation of the four C-H bonds is formed T2 irreducible representation. How predict and Raman active C-H stretching vibratio 33 to the Ta point group (found below). The reducible our C-H bonds is formed from one A irreducible representation and one presentation. How many infrared active C-H stretching vibrations would you Raman active C-H stretching vibrations would you predict for CHA? (4 points) Character table for T, point group Esc, 3c, 6s, 600 A1 1 1...