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Calculate ΔG°rxn,298 and ΔGrxn,298 for the following. a) Ag+(aq) + Cl-(aq) -> AgCl (s) b) Ag+(...
Consider the Gibbs energies at 25 ∘C. SubstanceSubstance ΔG∘f (kJ⋅mol−1)ΔGf∘ (kJ·mol−1) Ag+(aq)Ag+(aq) 77.177.1 Cl−(aq)Cl−(aq) −131.2−131.2 AgCl(s)AgCl(s)...
Consider the Gibbs energies at 25 ∘C. SubstanceSubstance ΔG∘f (kJ⋅mol−1)ΔGf∘ (kJ·mol−1) Ag+(aq)Ag+(aq) 77.177.1 Cl−(aq)Cl−(aq) −131.2−131.2 AgCl(s)AgCl(s) −109.8−109.8 Br−(aq)Br−(aq) −104.0−104.0 AgBr(s)AgBr(s) −96.9−96.9 (a) Calculate ΔG∘rxn for the dissolution of AgCl(s)AgCl(s). kJ⋅mol−1 (b) Calculate the solubility-product constant of AgCl. K= (c) Calculate ΔG∘rxnΔGrxn∘ for the dissolution of AgBr(s)AgBr(s). kJ⋅mol−1kJ⋅mol−1 (d) Calculate the solubility-product constant of AgBr. K=K=
NaCl(s) ⇌ Na+(aq) + Cl-(aq) ΔHo = 3.9 kJ/mol At 298 K, a saturated solution of NaCl has [Na+] = 7.0 M and [Cl-] = 5.4 M....
NaCl(s) ⇌ Na+(aq) + Cl-(aq)
ΔHo = 3.9 kJ/mol At 298 K, a saturated solution of NaCl has [Na+] =
7.0 M and [Cl-] = 5.4 M. If the temperature of the mixture is
increased to 323 K, what will be the equilibrium concentration (M)
of Na+? (Assume no ion pairing.) Enter your answer to 2 decimal
places.
NaCl(s) Na (aq) + CI'(aq) AH- 3.9 kJ/mol At 298 K, a saturated solution of NaCI has [Na"] 7.0M and [CI] -...
When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: Ag+(aq)+Cl−(aq)→AgCl(s)ΔH=−65.5kJ A.) Calculate...
When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: Ag+(aq)+Cl−(aq)→AgCl(s)ΔH=−65.5kJ A.) Calculate ΔH for formation of 0.100 mol of AgCl by this reaction. I got A ΔH=-6.55 kJ B.) Calculate ΔH for the formation of 2.80 g of AgCl. C.) Calculate ΔH when 0.110 mmol of AgCl dissolves in water. Need help with B and C.
Calculate the ΔG°rxn at 298 K using the following information. 2 HNO3(aq) + NO(g) → 3...
Calculate the ΔG°rxn at 298 K using the following information. 2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l) ΔG°rxn = ? ΔH°f (kJ/mol) -207.0 91.3 33.2 -285.8 S°(J/mol∙K 146.0 210.8 240.1 70.0
Calculate the standard change in Gibbs free energy, AG , for the given reaction at 25.0...
Calculate the standard change in Gibbs free energy, AG , for the given reaction at 25.0 "C. Consult the table of thermodynamic properties for standard Gibbs free energy of formation values. NH, CI() = NH(aq) + Cl" (aq) AGxn = kJ/mol Determine the concentration of NH(aq) if the change in Gibbs free energy, AGx. for the reaction is -9.39 kJ/mol. INH1 = Thermodynamic Properties at 298 K So 0 1 ΔΗ kJ/mol 0 105.8 -31.1 -32.6 -100.4 -127.0 -61.8 -124.4...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the reaction and comment on its value. (3 marks) (c) Determine the maximum work done available in the reaction. (3 marks) An equilibrium mixture, consisting of 0.5 atm of NHy(), 0.5 atm of HCKg) and excessive of NH Cl(s), is enclosed in a container at 298 K...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol 0 0 210.5 70.18 Ho (g) Hg (1) Hg,CI, (s) Ag (s) Agor(s AgCl(s) 0 265.37 106.76 -96.90 -109.80 0 -628.8 - 1582.3 -100.37 -127.01 0 -704 2 -1675.7 0 1 (g) AICI, (s) Al O (5) Ar (9) Au (s) BaSO's) 0 K(s) KBr(s) KCI (s) 0 -393.8 436.5 -567.3 -327.9 0 -1362.3 380.7 -408.5...
B. Calculate the standard entropy change for the reaction 2Na(s)+Cl2(g)?2NaCl(s) using the data from the following t...
B. Calculate the standard entropy change for the reaction
2Na(s)+Cl2(g)?2NaCl(s)
using the data from the following table:
Substance
?H?f (kJ/mol)
?G?f (kJ/mol)
S? [J/(K?mol)]
Na(s)
0.00
0.00
51.30
Cl2(g)
0.00
0.00
223.1
NaCl(s)
-411.0
-384.0
72.10
Express your answer to four significant figures and include the
appropriate units.
Part A Predict the sign of the entropy change, AS°,for each of the reaction displayed. Drag the appropriate items to their respective bins. Ag+(aq) + Cl-(aq) → AgCl(s) | | Ca(OH)2(s) →...
Calculate the cell potential for the following reaction as written at 25.00 °C, given that [Mg2...
Calculate the cell potential for the following reaction as written at 25.00 °C, given that [Mg2 ] = 0.774 M and [Sn2 ] = 0.0190 M. Standard reduction potentials can be found here. Reduction Half-Reaction Standard Potential Ered° (V) F2(g) + 2e– → 2F–(aq) +2.87 O3(g) + 2H3O+(aq) + 2e– → O2(g) + 3H2O(l) +2.076 Co3+(aq) + e– → Co2+(aq) +1.92 H2O2(aq) + 2H3O+(aq) + 2e– → 2H2O(l) +1.776 N2O(g) + 2H3O+(aq) + 2e– → N2(g) + 3H2O(l) +1.766 Ce4+(aq) + e– → Ce3+(aq)...
Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
NaCl(s) ⇌ Na+(aq) + Cl-(aq)
ΔHo = 3.9 kJ/mol At 298 K, a saturated solution of NaCl has [Na+] =
7.0 M and [Cl-] = 5.4 M. If the temperature of the mixture is
increased to 323 K, what will be the equilibrium concentration (M)
of Na+? (Assume no ion pairing.) Enter your answer to 2 decimal
places.
NaCl(s) Na (aq) + CI'(aq) AH- 3.9 kJ/mol At 298 K, a saturated solution of NaCI has [Na"] 7.0M and [CI] -...
Calculate the standard change in Gibbs free energy, AG , for the given reaction at 25.0 "C. Consult the table of thermodynamic properties for standard Gibbs free energy of formation values. NH, CI() = NH(aq) + Cl" (aq) AGxn = kJ/mol Determine the concentration of NH(aq) if the change in Gibbs free energy, AGx. for the reaction is -9.39 kJ/mol. INH1 = Thermodynamic Properties at 298 K So 0 1 ΔΗ kJ/mol 0 105.8 -31.1 -32.6 -100.4 -127.0 -61.8 -124.4...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the reaction and comment on its value. (3 marks) (c) Determine the maximum work done available in the reaction. (3 marks) An equilibrium mixture, consisting of 0.5 atm of NHy(), 0.5 atm of HCKg) and excessive of NH Cl(s), is enclosed in a container at 298 K...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol 0 0 210.5 70.18 Ho (g) Hg (1) Hg,CI, (s) Ag (s) Agor(s AgCl(s) 0 265.37 106.76 -96.90 -109.80 0 -628.8 - 1582.3 -100.37 -127.01 0 -704 2 -1675.7 0 1 (g) AICI, (s) Al O (5) Ar (9) Au (s) BaSO's) 0 K(s) KBr(s) KCI (s) 0 -393.8 436.5 -567.3 -327.9 0 -1362.3 380.7 -408.5...
B. Calculate the standard entropy change for the reaction
2Na(s)+Cl2(g)?2NaCl(s)
using the data from the following table:
Substance
?H?f (kJ/mol)
?G?f (kJ/mol)
S? [J/(K?mol)]
Na(s)
0.00
0.00
51.30
Cl2(g)
0.00
0.00
223.1
NaCl(s)
-411.0
-384.0
72.10
Express your answer to four significant figures and include the
appropriate units.
Part A Predict the sign of the entropy change, AS°,for each of the reaction displayed. Drag the appropriate items to their respective bins. Ag+(aq) + Cl-(aq) → AgCl(s) | | Ca(OH)2(s) →...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
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