Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also calculate ΔS ° for this reaction from standard entropies at 25°C. Use these values to calculate ΔG ° for the reaction at this temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
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Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
Calculate AG for the following reaction at 25°C. 2 Ca(s) + O2(g) → 2 Ca(s) (J/K mol) Substance AH (kJ/mol AG (kJ/mol) Ca(s) Ca2+(aq) CaO(s) Ca(OH)2(5) CaF2(5) CaCl(s) O(g) 028) O3(aq) Oz(8) -542.96 -635.6 -986.6 -1,214.6 -794.96 249.4 -553.0 -604.2 -896.8 -1,161.9 -750.19 230.1 41.6 -55.2 39.8 83.4 68.87 113.8 160.95 205.0 110.88 237.6 -12.09 142.2 16.3 163.4
0 AH; (kl mol-1) 90.37 33.8 81.57 9.67 Ca(s) 0 11 Review Intelligent Tutoring Problem 6.93 Using the data in the table below, calculate AH° in kilojoules for the following reactions. Standard Enthalpies of Formation of Typical Substances Substance AH() mol-1) Substance AH (K) mol-1) Substance Ag(s) H2O2(0) -187.6 CH (8) AgBr() -100.4 HBrg) -36 CH,OH(I) AgCl(s) - 127.0 HCl(g) -92.30 AO) HI(g) 26.6 CaBr20) Al2O3() -- 1669.8 HNO3(1) -173.2 CaCO3(9 CG) (graphite) H2SO4) -811.32 CaCl (5) CO(g) -110.5...
The following questions refer to the following reaction at 25°C and 1 atm. 2Fe(s) + (3/2)O2(g) + 3H2O(1) ► 2Fe(OH)3(3) AH = -789 kJ/mol Substance Fe(OH)3(S) Fe(s) O2(g) H2O(1) Sº (J/mol K) 107 27 205 70 7. Determine ASgurr for the reaction (in kJ/mol K) A) 3.14 B) 0.937 C) 0.378 D) 1.31 E) 2.65 8. Determine ASuniv for the reaction (in kJ/mol K) A) 0.23 B) 2.3 C) 0.36 D) 2.8 E) 3.6
Use the data from this table of thermodynamic properties to calculate the values of ASixn for each reaction at 25 °C. 4NH,(g) + 70,(9) — 4NO2(g) + 6H2O(g) AS:n = J/mol K N,() + 0,(g) 2 NO(g) J/mol K Asian = MISU415) -1065.25 N2(9) N2H4(0) 50.6 N20(9) 81.6 N204(9) 11.1 N205(9) 13.3 NH3(9) -45.9 NH3(aq) -80.29 NH,+(aq) -133.3 NH4CI(S) -314.4 NH4NO3(s) -365.6 (NH2)2CO(s) -333.1 Na(s) Na+(aq) -240.3 Na2CO3(S) -1130.7 NaCl(s) -411.2 NaF(s) -576.6 NaBr(s) -361.1 Nal(s) -287.8 NaNO3(s) -467.9 NaOH(s)...
Consider the reaction 2 CO2(g) +5 H2(e) C H2(e) + 4H2O(g) Using the standard thermodynamic data in the tables linked above, calculate the equilibrium constant for this reaction at 298.15K ANSWER: Submit Answer Retry Entire Group more group attempts remaining AH,(kJ/mol) AG® (kJ/mol) Sº (J/mol K) -238.7 -116.0 126.8 219.0 -363.0 249.0 135.1 -166.3 -110.0 -351.0 125.0 209.2 68.2 - 129.0 202.0 226.7 200.9 52.3 - 166.0 -53.0 -277.7 219.6 250.0 242.0 160.7 -13.0 -235.1 282.7 Carbon CH3OH (1) H2CO...
Use standard enthalpies of formation (in Appendix G in text) to calculate ∆H°rxn for each reaction. ∑ m∆H°f (products) - ∑n∆H°f (reactants), where m and n are coefficients. C2H4(g) + H2(g) ----- > C2H6(g) CO (g) + H2O (g) ----- > H2(g) + CO2(g) 3NO2(g) + H2O (l) ----- > 2HNO3(aq) + NO (g) 2SO2(g) + O2(g) -----------> 2SO3(g) 2C4H10 (g) + 13O2 (g) -----------> 8CO2 (g) + 10H2O (g) Substance --- ΔH° (kJ mol–) --- ΔG° (kJ mol–1) --- S°298 (J K–1 mol–1) C2H4 52.4 86.4 219.3 H2 0 0 130.7 C2H6 -84.0 -32.0 229.2 CO -110.52 -137.15 197.7 H2O -285.83 -237.1 70.0 CO2 -393.51 -394.36 213.8 NO2 33.2 51.30 240.1 NO 90.25 87.6 210.8 SO2 -296.83 -300.1 248.2 O2 0 0 205.2 SO3 -395.72 -371.06 256.76
1. 2. * Incorrect. What is the heat of formation of elements in their standard states? Did you use the correct equation of products minus reactants? The amino acid glycine, C2H5NO2, is one of the compounds used by the body to make proteins. The equation for its combustion is 4C2H5NO2(s) + 902(g) + 8C02(g) +10H20(1) +2N2(0) For each mole of glycine that burns, 973.49 kJ of heat is liberated. Use this information, plus values of AHF for the products of...
2) Thermochemical data are given below (at T=25.0°C) and may be useful in doing the following problem. Substance ΔΗ, AG (kJ/mol (J/mol K) (kJ/mol) Mg?"(aq) - 466.9 - 138.1 - 454,8 Mg(OH):(s) -924.7 63.1 - 833.9 - 230.0 . 10.8 - 1572 OH(aq) Using only the data above, find AG, AS ra, and K for the reaction Mg(OH):(8) Mg?" (aq) + 2 OH"(aq) [18 points)
4. Calculate the energy change for the following reaction, using the standard enthalpies of formation provided. SO2Cl2 (I)+2 H2O (I)2 HCI (g) + H,SO4 ) Substance AH (/mol) SO-ClO H2O0) HO(g) НСКО НС 9) H2SO 0) H-SO (aq) -394.1 -285.8 -241.8 92.3 -167.2 814.0 -909.3 If 25.0 kJ of heat energy is added to 50.0 g of water initially at 25°C, what will be the final temperature of the water? The specific heat of water is 4.18 J g1 °C