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04-09-2019 Each of the next questions will be graded over 10 points. Answer 80 points. 1. Which o...
Please answer Draw the following complexes, label (cis- and trans and fac- and mer-] A Dibromo...
Please answer
Draw the following complexes, label (cis- and trans and fac- and mer-] A Dibromo chloro diethylenetriamminerhenium (I). (5 isomers) B) Naz [Ru (ox)] (2 isomers) () Bis (bpy) Rh (II)-M-Oxo-M- hydrado-bis(en) Ir (III) D) Diammine dichloroplatinum (II) (2 isomers)
I need help with 7 and 8 pls! My answers are incorrect, I'd really appreciate an...
I need help with 7 and 8 pls! My answers are
incorrect, I'd really appreciate an explanation on
any correct answers, as this stuff is difficult for me to
understand!
#6 is just a visual and is correct!
Thank you!
n). Which (Fe(ox) Bryl 6. The Avalateliaand lov) is a bidentate ligand just like ethylenediamine (en). Which I . complexes (a,b or f) are optical isomers of each other? Ask yourself, which are mirror imag Brir. Cim. Br 2 bidnate...
1. Answer all parts to this question. From the following list of metal ions and ligands,...
1. Answer all parts to this question. From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation (Only one example is required for each part of the question, eg [Fe(H:01) Metal ions Ligands in order of increasing ligand field strength) I <Br <C<NO, <OHOXH.0 Ti(IV), V(III), V(IV), CHIT), CHIIT), Min(II). NH<em<bry<PPh<N =CÓ Mn(III). Mn(IV), Fe(II) Fe(III). CoII), COIIT) en = ethylenediamine...
Please take your time to answer all questions clearly and correctly... More Nomenclature and Symmetry Learning...
Please take your time to answer all questions clearly and
correctly...
More Nomenclature and Symmetry Learning Objectives: 1, Determine the rules for naming coordination compounds including special orientation of ligands 2. Use the rules to determine structures and formula from names and vice versa. 1. Isomerism in metal complex nomenclature: For the remainder of this assignment you can reference Figure 1 which contains a collection of metal complex structures with their chemical names and chemical compositions. Answer questions a -e....
NUM 55) How many stereogenic centers are present in the following compound County Name: it Name: A) 1 B) 2 ourse: D...
NUM 55) How many stereogenic centers are present in the following compound County Name: it Name: A) 1 B) 2 ourse: D) 4 Section: 56) Which of the following molecules are achiral? Exam D) I, II A) I, IV B) II, III C) III, IV 57) Which of the following molecules are chiral? I. cis-1,3-Dibromocyclohexane II. 1-Bromo-1-methylcyclohexane III. trans-1-Bromo-3-methylcyclohexane IV. cis-1-Bromo-3-methylcyclohexane A) II, III B) III, IV C) 1, IV D) 1, 58) Which of the following statements is true?...
1. For each pair of complexes given below (a-e), predict which complex will be more prone...
1. For each pair of complexes given below (a-e), predict which complex will be more prone to decomposition by reductive elimination. Briefly give your reasoning. a) PdMean2-dppe)] or [PtMe2(n2-dppe)] b) [PdMe2(n2-dppe)] or [PdMe2(n2-depe)] c) trans-[PdMe2(PPhs)2] or cis-[PdMe2(PPhs)2] d) [AuMe4)'or cis-TrMe2(PMe3)2]. e) [PdBr(?-dppe)] or [PdH(Me)(?2-dppe)] dppe-1 ,2-bis(diphenylphosphino)ethane depe 1,2-bis(dicyclohexylphosphino)ethane
1. For each of the following complexes, give the electron configurations of the d-type M Os,...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
Below is just an example to help answer my questions. 1. What is the difference betweeen...
Below is just an example to help answer my questions.
1. What is the difference betweeen geometric and optical isomers
and how can you identify them?
17. Which complexes exhibit geometric isomerism? I. [Cr(NH3)s(OH)]2* I. [Cr(en)2C2] III. [Cr(H2O)(NH3)3Cl2] A. I and II B. I and III C. Il and III D. All of them 18. Which of the following complexes has an optical isomer? NH2 A. I only B. Il only C. Both D. Neither NH3, NH3, Br Br NH3...
How many of the following statements are true?
19) How many of the following statements are true? i) Enantiomers are always chiral ii) A molecule that has a plane of symmetry can never be chiral. iii) An achiral molecule will always have an enantiomer. iv) A chiral molecule will always have an enantiomer v) Enantiomers are always nonsuperimposable a) 0 b) 1 c) 2 d) 3 e) 4 ab) 520. Identify the stereochemistry in each of the following compounds as R or S.Give the correct IUPAC name for the following compounds. For alkenes, when appropriate, indicate...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in o...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
Please answer
Draw the following complexes, label (cis- and trans and fac- and mer-] A Dibromo chloro diethylenetriamminerhenium (I). (5 isomers) B) Naz [Ru (ox)] (2 isomers) () Bis (bpy) Rh (II)-M-Oxo-M- hydrado-bis(en) Ir (III) D) Diammine dichloroplatinum (II) (2 isomers)
I need help with 7 and 8 pls! My answers are
incorrect, I'd really appreciate an explanation on
any correct answers, as this stuff is difficult for me to
understand!
#6 is just a visual and is correct!
Thank you!
n). Which (Fe(ox) Bryl 6. The Avalateliaand lov) is a bidentate ligand just like ethylenediamine (en). Which I . complexes (a,b or f) are optical isomers of each other? Ask yourself, which are mirror imag Brir. Cim. Br 2 bidnate...
1. Answer all parts to this question. From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation (Only one example is required for each part of the question, eg [Fe(H:01) Metal ions Ligands in order of increasing ligand field strength) I <Br <C<NO, <OHOXH.0 Ti(IV), V(III), V(IV), CHIT), CHIIT), Min(II). NH<em<bry<PPh<N =CÓ Mn(III). Mn(IV), Fe(II) Fe(III). CoII), COIIT) en = ethylenediamine...
Please take your time to answer all questions clearly and
correctly...
More Nomenclature and Symmetry Learning Objectives: 1, Determine the rules for naming coordination compounds including special orientation of ligands 2. Use the rules to determine structures and formula from names and vice versa. 1. Isomerism in metal complex nomenclature: For the remainder of this assignment you can reference Figure 1 which contains a collection of metal complex structures with their chemical names and chemical compositions. Answer questions a -e....
NUM 55) How many stereogenic centers are present in the following compound County Name: it Name: A) 1 B) 2 ourse: D) 4 Section: 56) Which of the following molecules are achiral? Exam D) I, II A) I, IV B) II, III C) III, IV 57) Which of the following molecules are chiral? I. cis-1,3-Dibromocyclohexane II. 1-Bromo-1-methylcyclohexane III. trans-1-Bromo-3-methylcyclohexane IV. cis-1-Bromo-3-methylcyclohexane A) II, III B) III, IV C) 1, IV D) 1, 58) Which of the following statements is true?...
1. For each pair of complexes given below (a-e), predict which complex will be more prone to decomposition by reductive elimination. Briefly give your reasoning. a) PdMean2-dppe)] or [PtMe2(n2-dppe)] b) [PdMe2(n2-dppe)] or [PdMe2(n2-depe)] c) trans-[PdMe2(PPhs)2] or cis-[PdMe2(PPhs)2] d) [AuMe4)'or cis-TrMe2(PMe3)2]. e) [PdBr(?-dppe)] or [PdH(Me)(?2-dppe)] dppe-1 ,2-bis(diphenylphosphino)ethane depe 1,2-bis(dicyclohexylphosphino)ethane
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
Below is just an example to help answer my questions.
1. What is the difference betweeen geometric and optical isomers
and how can you identify them?
17. Which complexes exhibit geometric isomerism? I. [Cr(NH3)s(OH)]2* I. [Cr(en)2C2] III. [Cr(H2O)(NH3)3Cl2] A. I and II B. I and III C. Il and III D. All of them 18. Which of the following complexes has an optical isomer? NH2 A. I only B. Il only C. Both D. Neither NH3, NH3, Br Br NH3...
19) How many of the following statements are true? i) Enantiomers are always chiral ii) A molecule that has a plane of symmetry can never be chiral. iii) An achiral molecule will always have an enantiomer. iv) A chiral molecule will always have an enantiomer v) Enantiomers are always nonsuperimposable a) 0 b) 1 c) 2 d) 3 e) 4 ab) 520. Identify the stereochemistry in each of the following compounds as R or S.Give the correct IUPAC name for the following compounds. For alkenes, when appropriate, indicate...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
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