A)Phosogene (mustard gas) reacts with equal amounts of ethoxide and methoxide. Draw the 4 product...
a)Phosogene (mustard gas) reacts with equal amounts of ethoxide and methoxide. Draw the 4 products and their respective ratios
b) Acyl halide (RCOCl) reacts with 1 eq. NaOH, carboxylic acid forms. What other products can form. Draw as many as possible.
Homework Answers
(b) RCOCl + NaOH = RCOOH + NaCl
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A)Phosogene (mustard gas) reacts with equal amounts of ethoxide and methoxide. Draw the 4 product...
20.14 ULUS because they result in the transfer of an wety np. from one heterontom to...
20.14
ULUS because they result in the transfer of an wety np. from one heterontom to another is prepared by the acetylation of morphine, an analyesic compound Isolated from the opium poppy. Both OH groups of morphine are readily acetylated with ceris whydride to form the diester present in heroin. HO OT o HF HOW Problem 20.14 morphine heroin minyarides react like acid chlorides with the nucleophiles described in Chapter 17. draw the products formed when each of the following...
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in...
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in methanol (Na* OCH, CH,OH). CH NaOme MeOH CH Compound A Problem 2c Draw the major expected organic product (a) Redraw Compound A as seen in Viewpoint I below left as a Newman projection on the template provided in Problem 2a (below). Hint: Fill in missing Hs ar C2 and C3 to help you get started! (b) Rotate the C2 C3 bond to obtain the...
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c)...
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c) ОН ОН (d) Br ОН ОН NH2 2) Draw the condensed and line structures for the following compounds (a) 3,4-dimethylhexanoic acid (b) Phenylacetic acid (c) 3,4-dinitrobenzoic acid (d) 2,2,3-triflurobutanoic acid (e) 3-hydroxybutanoic acid (1) o-hydroxybenzoic acid (g) a-aminopropionic acid 3) Name the following dicarboxylic acids (use both IUPAC and common names) Он (а) НО ОН НО. (b) он ОН ОН (d) ОН он ОН...
please answer them fast 4 a) Shows the is stmturobezeme with abndingboding and nodes? Cy b) Number of nodes increases as the MOs increases in energy, Is it True/False-Explain? (2) 5 a) Draw all...
please answer them fast
4 a) Shows the is stmturobezeme with abndingboding and nodes? Cy b) Number of nodes increases as the MOs increases in energy, Is it True/False-Explain? (2) 5 a) Draw all the possible resonance structure of cyclopentadienyl cation? (2) b) Is it aromatic or antiaromatic and why? (2) 6. a) Mixed acid nitration of Chlorobenzene 64% p-nitro product will form-explain? (2) will give only 1% m-nitro product whereas about vating groups are usually stronger directors than deactivating...
Chlorine gas reacts with phosphorus to produce phosphorus pentachloride as shown in the chemical equation below. What i...
Chlorine gas reacts with phosphorus to produce phosphorus pentachloride as shown in the chemical equation below. What is the maximum number of grams of PCls are produced from 3.5 g of Cl2 and excess P? 5C12(g) + 2P(s) → 2PC13(s) 2) What is the theoretical yield of chromium that can be produced by the reaction of 40.0 g of Cr2O3 with 8.00 g of aluminum according to the unbalanced chemical equation below? Al(s) + Cr2O3(s) → Al2O3(s) + Cr(s) Ammonia...
for the reaction: acetaminophen + (NaOH/EtOH note: etoh is ethanol) and butyl iodide ---------------> 4-butoxyacetanilide a)...
for the reaction: acetaminophen + (NaOH/EtOH note: etoh is ethanol) and butyl iodide ---------------> 4-butoxyacetanilide a) The first step in this reaction is to reflux acetaminophen in a NaOH/EtOH solution, followed by the addition of butyl iodide. What is the purpose of using the NaOH/EtOH solution? Would the SN2 reaction still occur if the first step was not completed? Why or why not? b) Upon completion of the reaction (before filtration), an additional 4.0 mL of 1.0 M NaOH/EtOH was...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of using chromic acid as the oxidizing agent, you wed concentrated sulfuric acid. em to show the oxidation of cyclohexanol to cyclohexanone. W 1. Waite a mechanism to show the oxidatinast 개 wi 2. How would you carry out the following transformation? GENERAL EXPERIMENTAL ORGANIC CHEMIST action (If it has a name) and 3. Some of the reactions below are write the products of each...
A. Balance the following equations by adding coefficients. Do not leave blank spaces - use a...
A. Balance the following equations by adding coefficients. Do not leave blank spaces - use a "1" if necessary. Identify the type of reaction in the right column. Balanced Equation Type of Reaction 1. H.As2O7 → _ As2O3 + _H20 2. _N2+_02—_N20 _NaI + _Br2 → _NaBr +_12 PbCrO4 +_HNO3 → __Pb(NO3)2 + __H2CrO4 . _C3H8 +_02 → __CO2 + __H20 TiCl4 + _ Mg → _ MgCl2 + ____Ti CuSO4 +_ KCN → ___Cu(CN)2 +_K2SO4 Ca(ClO3)2 → _ CaCl2...
Please draw the mechanism with the compounds listed below 4 9-4: Transesterification For this assignment, the...
Please draw the mechanism with the compounds listed below 4
9-4: Transesterification For this assignment, the target compound that you should synthesize is ethyl propionate. This is a carboxylic acid derivative transformation. Keep in mind the mechanism and the potential of reaction reversibility. Examine the product and determine the bond that will be formed. Synthesis Procedures 1. Start Virtual ChemLab and select Transesterification from the list of assignments on the whiteboard. After entering the synthesis laboratory, use the available reagents...
The proton nmr and the infrared spectra of DCC, DMAP, DCU, the product and the nmrs...
The proton nmr and the infrared spectra of DCC, DMAP, DCU, the
product and the nmrs of the starting materials and products are
shown. These are labeled Compounds A, B and C. a.Which nmr is the
product?
b. Which is the nmr of the starting material?
c. What is the mixture of compounds shown as compound C?
tert-Butyl Ethyl Fumarate DCC, DMAP, CHCI OH Chemical Formula: C,H,O Chemical Formula: CH 0 Molecular Weight: 144.13 Molecular Weight: 74.12 Chemical Formula: CH...
20.14
ULUS because they result in the transfer of an wety np. from one heterontom to another is prepared by the acetylation of morphine, an analyesic compound Isolated from the opium poppy. Both OH groups of morphine are readily acetylated with ceris whydride to form the diester present in heroin. HO OT o HF HOW Problem 20.14 morphine heroin minyarides react like acid chlorides with the nucleophiles described in Chapter 17. draw the products formed when each of the following...
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in methanol (Na* OCH, CH,OH). CH NaOme MeOH CH Compound A Problem 2c Draw the major expected organic product (a) Redraw Compound A as seen in Viewpoint I below left as a Newman projection on the template provided in Problem 2a (below). Hint: Fill in missing Hs ar C2 and C3 to help you get started! (b) Rotate the C2 C3 bond to obtain the...
1) Name the following carboxylic acids (use both IUPAC and common names): ОН ОН (b) (c) ОН ОН (d) Br ОН ОН NH2 2) Draw the condensed and line structures for the following compounds (a) 3,4-dimethylhexanoic acid (b) Phenylacetic acid (c) 3,4-dinitrobenzoic acid (d) 2,2,3-triflurobutanoic acid (e) 3-hydroxybutanoic acid (1) o-hydroxybenzoic acid (g) a-aminopropionic acid 3) Name the following dicarboxylic acids (use both IUPAC and common names) Он (а) НО ОН НО. (b) он ОН ОН (d) ОН он ОН...
please answer them fast
4 a) Shows the is stmturobezeme with abndingboding and nodes? Cy b) Number of nodes increases as the MOs increases in energy, Is it True/False-Explain? (2) 5 a) Draw all the possible resonance structure of cyclopentadienyl cation? (2) b) Is it aromatic or antiaromatic and why? (2) 6. a) Mixed acid nitration of Chlorobenzene 64% p-nitro product will form-explain? (2) will give only 1% m-nitro product whereas about vating groups are usually stronger directors than deactivating...
Chlorine gas reacts with phosphorus to produce phosphorus pentachloride as shown in the chemical equation below. What is the maximum number of grams of PCls are produced from 3.5 g of Cl2 and excess P? 5C12(g) + 2P(s) → 2PC13(s) 2) What is the theoretical yield of chromium that can be produced by the reaction of 40.0 g of Cr2O3 with 8.00 g of aluminum according to the unbalanced chemical equation below? Al(s) + Cr2O3(s) → Al2O3(s) + Cr(s) Ammonia...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of using chromic acid as the oxidizing agent, you wed concentrated sulfuric acid. em to show the oxidation of cyclohexanol to cyclohexanone. W 1. Waite a mechanism to show the oxidatinast 개 wi 2. How would you carry out the following transformation? GENERAL EXPERIMENTAL ORGANIC CHEMIST action (If it has a name) and 3. Some of the reactions below are write the products of each...
A. Balance the following equations by adding coefficients. Do not leave blank spaces - use a "1" if necessary. Identify the type of reaction in the right column. Balanced Equation Type of Reaction 1. H.As2O7 → _ As2O3 + _H20 2. _N2+_02—_N20 _NaI + _Br2 → _NaBr +_12 PbCrO4 +_HNO3 → __Pb(NO3)2 + __H2CrO4 . _C3H8 +_02 → __CO2 + __H20 TiCl4 + _ Mg → _ MgCl2 + ____Ti CuSO4 +_ KCN → ___Cu(CN)2 +_K2SO4 Ca(ClO3)2 → _ CaCl2...
Please draw the mechanism with the compounds listed below 4
9-4: Transesterification For this assignment, the target compound that you should synthesize is ethyl propionate. This is a carboxylic acid derivative transformation. Keep in mind the mechanism and the potential of reaction reversibility. Examine the product and determine the bond that will be formed. Synthesis Procedures 1. Start Virtual ChemLab and select Transesterification from the list of assignments on the whiteboard. After entering the synthesis laboratory, use the available reagents...
The proton nmr and the infrared spectra of DCC, DMAP, DCU, the
product and the nmrs of the starting materials and products are
shown. These are labeled Compounds A, B and C. a.Which nmr is the
product?
b. Which is the nmr of the starting material?
c. What is the mixture of compounds shown as compound C?
tert-Butyl Ethyl Fumarate DCC, DMAP, CHCI OH Chemical Formula: C,H,O Chemical Formula: CH 0 Molecular Weight: 144.13 Molecular Weight: 74.12 Chemical Formula: CH...
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