H2CrO4 is a strong oxidizing agent and oxidize the Alcohol to Carboxylic acids.
Claisen condensation reaction Gives beta keto ester.
Reaction of Ester with excess Grignard reagent gives tertiary alcohol.
Gilmanns reagent R2CuLi undergo conjugate addition.
1. Propose a sequence of reactions that efficiently converts the given starting material(s) to th...
1) Propose a sequence of reactions that efficiently converts the given starting material(s) to the target molecule. Draw the structure of the product formed after each synthetic step. Do not write mechanisms. c) NH2 HN racemic
1) Propose a sequence of reactions that efficiently converts the given starting material(s) to the target molecule. Draw the structure of the product formed after each synthetic step. Do not write mechanisms. c) NH2 HN racemic
1. Propose a sequence of reactions that efficiently converts the
given starting material(s) to the target molecule. Draw the
structure of the product formed after each synthetic step. Do not
write mechanisms.
c) 2x TBSO
c) 2x TBSO
(3) Propose an efficient synthesis of target molecules (a) and (b). All of the carbons in the targets must come from one of the compounds below. Draw the structure of the product formed after each synthetic step. Do not write mechanisms. Note Points off for long, inefficient syntheses Нас CH3I OEt OEt H-C CH methyl iodide ethyl 2-butenoate ethyl acetoacetate he ptane-2,6-dione H2C он CH
Provide a sequence of reaction to convert the starting material
to the product. Show all reagents and synthetic intermediates. You
can use any addition carbon sources if needed but you must use the
starting material given. The mechanisms do not have to be
shown.
Synthesis 1. The following transformations cannot be perfor Uwing transformations cannot be performed in one step. Provide a sequence of reactions 10 convert the "starting material" to the "product." Show all the reagents and synthetic intermediates....
Propose the starting material for each product from a molecule with the given formula in the reactants box. You do not have to show mechanisms, but use any reagents you require for each problem. Each problem is ONE OF TWO retrosynthetic steps to the starting materials and all steps should be described CH, Br C Hia 4. Propose a mechanism for the reaction below, showing the movement of every pair of electrons. Draw in an energy diagram, labeling, with structures,...
4. propose the synthesis of preparing the target from its corresponding starting material. Show the product/s formed in each step. Mechanisms are not required. steps
Synthesis 1. The following transformations cannot be performed in one step. Provide a sequence of reactions to convert the "starting material to the "product." Show all the reagents and synthetic intermediates. You can use any additional carbon sources if needed, but you must use the starting material given. Br -ОН Br
Synthesis 1. The following transformations cannot be performed in one step. Provide a sequence of reactions to convert the "starting material" to the "product. Show all the reagents and synthetic intermediates. You can use any additional carbon sources if needed, but you must use the starting material given. "он но 1 Он он Br 1 K
Draw the missing major organic product(s), starting
material(s), or reagents for each of the following reactions (DO
NOT WRITE +EN AS A PRODUCT (ie draw everything out!)! And remember
stereo and regiochemistry.) Assume reagents are in excess unless
otherwise indicated. **To make things simple, I indicated what is
needed for each section! Please don't just put the answers, but
explanations as well on why. Thanks!
a) draw the starting material for this reaction.
b) draw the product for this reaction....
Synthesis The following transformations cannot be performed in one step. Provide a sequence of reactions to 1. convert the "starting material" to the "product." Show all the reagents and synthetic intermediates You can use any additional carbon sources if needed, but you must use the starting material given. H но он Br 1