Thermodynamic Data at 25 oc Substance CH4 (g) AHP(kJmol 74.6 10.5 AGP(kJ/mo) 50.5 137.2 223.1 Cl2 (g) 157.3 129.7 8 92.3 8 2 H20 (g) 2 3 3 H2S (g) 6 103.7 2 45.9 4 AgNO3 (s 296.8 3 0 300.1 3 371.1 320.5 6 1
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2 NH3 (9)+ 3 o2(9) > 3 H20 (9) + NO2 (9) + NO (9) Use the data from this link:ThermodynamicData to calculate the following for the reaction above. (a)AG° at 298 K. kJ (b) Calculate the numerical v...
Thermodynamic Data at 25 C Substance CH4 (B) (kJmol AHof 74.6 -110.5 AGof 50.5 -137.2 S...
Thermodynamic Data at 25 C Substance CH4 (B) (kJmol AHof 74.6 -110.5 AGof 50.5 -137.2 S (Jmol 'K) 186.3 CO (B Cl2 (g) Cu (s) 197.7 223.1 33.2 42.6 Cuo (s) 157.3 -129.7 202.8 -92.3 -273.3 285.8 241.8 -173.23 -20.6 -95.3 -275.4 -237.1 -228.6 -79.9 33.4 186.9 173.8 70.0 188.8 155.6 205.8 HF H20 (9) HNO3 (1) 91.3 33.2 81.6 45.9 87.6 51.3 103.7 -16.4 191.6 210.8 240.1 220.0 192.8 NO2 (8) NH3 02 205.2 42.6 140.9 AgNO3 (s) 124.4...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction:...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction: NO(g) + O (9) NO2 (g), AG° = ? 2 03 (9) - 3 O2 (g), AG° = +489.6 kJ 02 (9) 20 (9), AGⓇ = +463.4 kJ NO(g) + O2 (9) - NO2 (g) + O2 (g), AG° = -199.5 kJ QUESTION 14 Calculate AG for the following reaction, in kJ, at 0 °C under the following non-standard conditions shown below. 2 Hgo...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction:...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction: NO2(g) + CO(g) NO(g) + CO2(g) 0 -222 kJ 0-990 kJ 0 - 199 kJ O-1211 kJ O-420 kJ AG; (kJ/mol ) at 25°c AH; Sº (kJ/mol) (KJ/K mol) AG, (kJ/mol) at 25°c ΔΗ: sº (kJ/mol) (kJ/kmol) 0.0 -20.6 H2S (g) -33.6 +0.2057 -814.0 H2SO4(0) +0.1569 -690.1 0.0 Hg(e) 0.0 +0.0760 -90.8 Hgo (3) -58.6 +0.0703 12 () 0.0 0.0 +0.1161 0.0 K(s) +0.0642...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the reaction and comment on its value. (3 marks) (c) Determine the maximum work done available in the reaction. (3 marks) An equilibrium mixture, consisting of 0.5 atm of NHy(), 0.5 atm of HCKg) and excessive of NH Cl(s), is enclosed in a container at 298 K...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction:...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction: NO2(g) + CO(g) + NO(g) + CO2(g) O-420 kJ 0-222 kJ O-1211 kJ 0-199 kJ 0-990 kJ 3 pts Question 27 What is the pH of .731 M H2CO3 (aq)? 8.4 O 5.2 O 3.3 O 6.5 10.7 Table 6 - Thermodynamic Data of 12.0 M HOH ZOH is added to Ag(s) AgBr(s) Agcl(s) AgI (8) AgNO, () Ag20(8) Al(a) Al,0, () Ba (3)...
#6-9 6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your...
#6-9
6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your book (Appendix 2): CH(g)+02(B) HO(g) + CO,(g) (not balanced) 7. Calcium carbonate decomposes at high temperature to form carbon dioxide and calcium oxide: CaCO3 CO2+ CaO Using data from the textbook (Apendix 2), determine the heat of reaction. 8. When potassium chloride reacts with oxygen under the right conditions, potassium chlorate is formed: 2 KCI+3 02 2KCIO3 Using data from the textbook (Appendix 2),...
Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C....
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
(6 pts.) 1. The air pressure in the inner tube of a tire on a typical...
(6 pts.) 1. The air pressure in the inner tube of a tire on a typical racing bike is held at a pressure of 115 psi (pounds! per square inch). Convert this pressure to atm and mm Hg. (3 pts. each) The atmospheric pressure is 0.978 atm. Determine the pressure of the enclosed gas in each of the cases depicted below. Gas Gas (6 pts.) 3. A 5.90 L bottle contains 1070 g of oxygen at 25.0°C. Calculate the pressure...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
Thermodynamic Data at 25 C Substance CH4 (B) (kJmol AHof 74.6 -110.5 AGof 50.5 -137.2 S (Jmol 'K) 186.3 CO (B Cl2 (g) Cu (s) 197.7 223.1 33.2 42.6 Cuo (s) 157.3 -129.7 202.8 -92.3 -273.3 285.8 241.8 -173.23 -20.6 -95.3 -275.4 -237.1 -228.6 -79.9 33.4 186.9 173.8 70.0 188.8 155.6 205.8 HF H20 (9) HNO3 (1) 91.3 33.2 81.6 45.9 87.6 51.3 103.7 -16.4 191.6 210.8 240.1 220.0 192.8 NO2 (8) NH3 02 205.2 42.6 140.9 AgNO3 (s) 124.4...
Use Hess' law and the data below to calculate AG, in kJ, for the following reaction: NO(g) + O (9) NO2 (g), AG° = ? 2 03 (9) - 3 O2 (g), AG° = +489.6 kJ 02 (9) 20 (9), AGⓇ = +463.4 kJ NO(g) + O2 (9) - NO2 (g) + O2 (g), AG° = -199.5 kJ QUESTION 14 Calculate AG for the following reaction, in kJ, at 0 °C under the following non-standard conditions shown below. 2 Hgo...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction: NO2(g) + CO(g) NO(g) + CO2(g) 0 -222 kJ 0-990 kJ 0 - 199 kJ O-1211 kJ O-420 kJ AG; (kJ/mol ) at 25°c AH; Sº (kJ/mol) (KJ/K mol) AG, (kJ/mol) at 25°c ΔΗ: sº (kJ/mol) (kJ/kmol) 0.0 -20.6 H2S (g) -33.6 +0.2057 -814.0 H2SO4(0) +0.1569 -690.1 0.0 Hg(e) 0.0 +0.0760 -90.8 Hgo (3) -58.6 +0.0703 12 () 0.0 0.0 +0.1161 0.0 K(s) +0.0642...
7 Consider the following reaction at 298 K: NH3(g) +HCI(g)NH4CI(s) Using the thermochemical data at 298 K given below (a) Determine the AH for the reaction. (2 marks) (b) Determine the AG for the reaction and comment on its value. (3 marks) (c) Determine the maximum work done available in the reaction. (3 marks) An equilibrium mixture, consisting of 0.5 atm of NHy(), 0.5 atm of HCKg) and excessive of NH Cl(s), is enclosed in a container at 298 K...
Use Table 6 values to calculate AGº (in kJ) at 2000 K for the following reaction: NO2(g) + CO(g) + NO(g) + CO2(g) O-420 kJ 0-222 kJ O-1211 kJ 0-199 kJ 0-990 kJ 3 pts Question 27 What is the pH of .731 M H2CO3 (aq)? 8.4 O 5.2 O 3.3 O 6.5 10.7 Table 6 - Thermodynamic Data of 12.0 M HOH ZOH is added to Ag(s) AgBr(s) Agcl(s) AgI (8) AgNO, () Ag20(8) Al(a) Al,0, () Ba (3)...
#6-9
6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your book (Appendix 2): CH(g)+02(B) HO(g) + CO,(g) (not balanced) 7. Calcium carbonate decomposes at high temperature to form carbon dioxide and calcium oxide: CaCO3 CO2+ CaO Using data from the textbook (Apendix 2), determine the heat of reaction. 8. When potassium chloride reacts with oxygen under the right conditions, potassium chlorate is formed: 2 KCI+3 02 2KCIO3 Using data from the textbook (Appendix 2),...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
(6 pts.) 1. The air pressure in the inner tube of a tire on a typical racing bike is held at a pressure of 115 psi (pounds! per square inch). Convert this pressure to atm and mm Hg. (3 pts. each) The atmospheric pressure is 0.978 atm. Determine the pressure of the enclosed gas in each of the cases depicted below. Gas Gas (6 pts.) 3. A 5.90 L bottle contains 1070 g of oxygen at 25.0°C. Calculate the pressure...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
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