Question

(20 pts) 6. (a) Consider a molecule with two Franck-Condon active vibrations with "Trequencies" Vi = 600 and v2=1500 cm-1, with displacement parameters λι = 1.0 and λ2-2.0 for electronic excitation to a certain excited electronic state. All other vibrations have λ=0. Make a table of the transition wavenumbers and Frack-Condon values for all vibronic transitions from the 0 vibrational level of the ground state that includes all combinations and overtones with vibrational energy below 4000 cm. (b) What fraction of the total intensity does the table account for?

Answer 1

nuolei onthe dio the うろこt-con 2- 2,兀 7 2 Nou

2 no