Consider a chloroform(1)ytetrahydrofuran(2) mixture with x1 080,
initially at 70C and 120 kPa
Describe the evolution of phases and phase compositions as the
temperature is gradually
increased to 80°C
Consider a chloroform(1)ytetrahydrofuran(2) mixture with x1 080, initially at 70C and 120 kPa Describe the evolution of phases and phase compositions as the temperature is gradually increased to 80°C
Consider the phase diagram below for a mixture of chloroform and methanol, looking at how the boiling point changes with composition at constant pressure. If you started with a solution that was Xchloroform = 0.1 at a temperature of 333 K, is it possible to use fractional distillation to purify this solution to nearly 100% chloroform? Approximately what concentration (in mole fraction) would you expect you could achieve through fractional distillation? Curves calculated by mod. UNIFAC (Dortmund) Temperature Minimum Azeotrope...
2. [25 points] The following figure shows the phase diagram of Cu-Ag alloy system. A mixture of Ag and Cu with a eutectic composition (or concentration) is heated to a high temperature and keep for enough time to prepare the material into a uniform liquid state. The material is then cooled down to 800°c. Cu-Ag System 1200 Liquid 800 A 600 400 100 80 60 40 20 wt% Ag a) What is the Ag composition in the original material so...
2. [25 points] The following figure shows the phase diagram of Cu-Ag alloy syst em. A mixture of Ag and Cu with a eutectic composition (or concentration) is heated to a high temperature and keep for enough time to prepare the material into a uniform liquid state. The material is then cooled down to 800°C. Cu-Ag System 1200p Liquid 1000 800 A B. 600 400 200 100 80 60 40 20 wt% Ag (o) What is the Ag composition in...
1 picture- problem 2 other pictures- phase diagrams for problem 1. Draw a phase diagram for a binary eutectic alloy with solid solubility, naming and describing the significance of the main features. The binary alloy system of metals A and B contains two intermediate (intermetallic) phases A B and AB2 of narrow composition range, each of which forms by a peritectic reaction A cutectic point also exists, at 85at% B. The melting point of A is higher than that of...
1. Below is the phase diagram of Pb-Sn alloy. (a) Describe what happens to a 20%-Pb 80%-Sn alloy as temperature decreases from 300 °C to 50 °C; use sketches as needed. (b) When temperature is kept constant at 200 °C, describe what happens as the Sn concentration is increased from 10 wt% to 90 wt%; use sketches as needed. 100% Liquid Procutectic α 24% Eutectic α Liquid 76% Eutectic β Alloy I Alloy 2 Liquid 49% 327 Liquidus 300 Liquid...
3. Consider the hexafluorobenzene(1)-cyclohexane(2) mixture at 50 °C. The vapor pressures for the pure species are psat = 34.10 kPa and Pat = 36.30 kPa. a. (10%) Assuming Raoult's law, calculate the pressure range of the 2-phase region when the mole fraction of hexaflourobenzene is 0.8. b. (10%) Experiments show that this mixture at 50°C has an azeotrope. Show mathematically that Raoult's law is unable to predict an azeotropic behavior. c. (10%) Use the modified Raoult's law with the van...
3. Consider the hexafluorobenzene(1)-cyclohexane(2) mixture at 50°C. The vapor pressures for the pure species are Prat = 34.10 kPa and Pat = 36.30 kPa. a. (10%) Assuming Raoult's law, calculate the pressure range of the 2-phase region when the mole fraction of hexaflourobenzene is 0.8. b. (10%) Experiments show that this mixture at 50-C has an azeotrope. Show mathematically that Raoult's law is unable to predict an azeotropic behavior. c. (10%) Use the modified Raoult's law with the van Laar...