Explain how δ- and λ-isomerism arises in transition metal complexes. Give an example of a complex that exhibits this kind of isomerism.
Explain how δ- and λ-isomerism arises in transition metal complexes. Give an example of a complex that exhibits this kind of isomerism.
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
For each of the following octahedral transition metal complexes, determine whether the complex will be paramagnetic or diamagnetic. Show how you came to each conclusion. The structure of the en ligand is shown below. [Mn(CN)6]3
2. Give the following transition metal complexes formulas from the name: Example: Potassium bis(oxalato)cuprate(II) dihydrate - Answer= K[Cu(ox)2).(H2O)2 (a) potassium ethylenediaminetetraacetate cobalt(III) (b) sodium dibromobis(ethylenediamine)cobalt(III) sulfate (c) calcium tetrachloro cuprate (1)
5. For each of the following transition metal complexes, give (i) the d-electron count, (ii) the approximate shape of the complex, and (iii) an energy level diagram showing the splitting and filling of the d-orbitals. (a) [Os(CN)6]3- (b) cis-PtCl2(NH3)2 (c) [Cu(NH3)4]*
2 A molecular orbital diagram for a tetrahedral transition metal complex is shown below. Show how the electrons occupy the molecular orbitals in the diagram for each complex (a)-(g). Why are low-spin, tetrahedral transition metal complexes rare? (a) [MnBra (d) [CuCl (b) [CrC (e) [NICI (c) IMnO (OsO (g) MoF ΔΤ e+t a+t 4L a (b) Identify the bonding, anti-bonding, and non-bonding orbitals in this diagram. M
How many electrons are in the valence d orbitals in these transition metal complexes && why? a.) [Co(en)2(H2O)2]2+ b.) [Mo(EDTA)]ClO4 c.) K3[ReCl6] P.S. en = ethylene diamine
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
10. Explain birefringence and give one example of a material that exhibits the property of birefringence.
1.- Define what are complex ions 2.- Using NiCl as a reactant look in a book or in the web for a reaction to form a complex ion, indicate which is the Lewis acid and which is the Lewis base. An example of your answer is this: Ag (aq) + 2NH, (aq) - Ag(NH),(aq) Lewis acid Lewis base 3.- Using the rules of nomenclature name the complex you have proposed in question 2 4.- Indicate the coordination number and geometry...
(1) In your own words, give an example of a choice that you make that exhibits the law of diminishing marginal utility. (2) Explain why the law of diminishing marginal utility is upheld for this choice. (3) How does this relate to your willingness and ability to buy the good?