1)
Given, the chemical reaction,
ammonium nitrite (aq) nitrogen(g) + water(l)
NH4NO2(aq) N2(g) + 2H2O(l)
Also given,
Moles of water = 0.880 mol
The mole ratio between ammonium nitrite and nitrogen is 1:2. Using the given moles of water and the mole ratio to calculate the number of moles of ammonium nitrite,
= 0.880 mol of H2O x ( 1 mol of NH4NO2 / 2 mol of H2O)
= 0.44 mol of NH4NO2
Converting the number of moles to grams,
= 0.44 mol of NH4NO2 x (64.06 g / 1mol)
= 28.2 g of NH4NO2
2) Given,
The reaction,
perchloric acid(HClO4)(aq) + tetraphosphorus decaoxide(s) phosphoric acid(aq) + dichlorine heptoxide(l)
12HClO4(aq) + P4O10(s) 4H3PO4(aq) + 6Cl2O7(l)
Also given,
Mass of HClO4 = 23.6 grams
Calculating the number of moles of HClO4 from the given mass,
= 23.6 g of HClO4 x ( 1 mol /100.46 g)
= 0.2349 mol of HClO4
Now, from the balanced reaction, the mole ratio between HClO4 and H3PO4 is 12: 4,
Using the calculated moles of HClO4 and the mole ratio, calculating the number of moles of phosphoric acid,
= 0.2349 mol of HClO4 x ( 4 mol of H3PO4 / 12 mol of HClO4)
= 0.0783 mol of H3PO4 will be produced
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