Homework Answers
1)
see experiment 1 and 2:
[NO] doubles
[H2] is constant
rate becomes 4 times
so, order of NO is 2
see experiment 2 and 3:
[NO] is constant
[H2] doubles
rate doubles
so, order of H2 is 1
overall order = 2 + 1 = 3
Rate law is:
rate = k*[NO]^2*[H2]
2)
Put values from 1st row of table in rate law
rate = k*[NO]^2*[H2]
2*10^-2 = k*0.00593^2*0.38^1
k = 1497 M-2.s-1
Answer: 1.50*10^3 M-2.s-1
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|References For the reaction N2(8) 2 H,0(8) 2 NO(g) +2 H3 (g) at 1100° C, the following data have been obtained. NO...
B1. The following experimental data were obtained for the following reaction at 1000 K: 2 NO(g)...
B1. The following experimental data were obtained for the following reaction at 1000 K: 2 NO(g) + O2(g) 2 NO2(g) NOI (mol L OJ (mol L- Inital rate of reaction (mol L-'s - 0.0100 0.0200 0.0300 0.0200 0.0500 0.0200 3.02 x 10-5 3.02 x 10-4 2.72 x 10-4 (a) Determine the order of the reaction for each reactant (b) Determine the overall order of the reaction. Answer: (c) Calculate the rate constant at this temperature.
For the reaction below, the following data were obtained at constant temperature. Reaction: A(g) + B(g)...
For the reaction below, the following data were obtained at constant temperature. Reaction: A(g) + B(g) + C(g) D(g) Exp't Initial [A] (mol/L) Initial [B] (mol/L) Initial [C] (mol/L) Initial Rate (mol/Ls) 1 0.0100 0.1500 0.0200 1.24 10-2 2 0.0200 0.1500 0.0200 2.48 10-2 3 0.0200 0.3000 0.0200 9.90 10-2 4 0.0100 0.1500 0.0400 1.24 10-2 (a) What is the order with respect to each reactant? with respect to [A]. with respect to [B]. with respect to [C]. (b) Select...
4. Suppose the following data is obtained for the reaction: 2NO(g)+2H2(g) → N2(g)+2H20(g) [NO] [Hz] Rate...
4. Suppose the following data is obtained for the reaction: 2NO(g)+2H2(g) → N2(g)+2H20(g) [NO] [Hz] Rate (mol L 54) 0.1 0.1 1.4 x 10-4 0.2 0.1 5.6 x 10-4 0.1 0.2 2.8 x 10-4 Determine the rate law for the reaction
onlocatori entale References The reaction NO(g) +0,() + NO.(k)+(s) plays a role in the formation of...
onlocatori entale References The reaction NO(g) +0,() + NO.(k)+(s) plays a role in the formation of titrogen dioxide in automobile engines Suppose a series of experiments measured the rate of this reaction at 500 K and produced the following data NO 101 rate - ANO]/A (01-L) (mol L-4) (mol-1,-1,) 0.00166 0.00415 5.51 x 10-17 0.00166 0.00830 1.10 x 10- 0.00498 0.00415 1.65 x 10-16 Derive a rate law for the reaction (Kate expressions take the general form: rate [ C...
1. The kinetics of the following reaction have been studied: N2 + 3 H2 → 2...
1. The kinetics of the following reaction have been studied: N2
+ 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as
∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1
(a) What is the rate of the reaction in mol L-1 s-1?
(b) What is ∆[N2]/∆t in mol L-1 s-1?
(c) What is ∆[H2]/∆t in mol L-1 s-1?
2. The initial rate of the reaction of species A and B A + 2 B →...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g) The following data were obtained...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g)
The following data were obtained from three experiments using
the method of initial rates:
3. Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) The following data were obtained from three experiments using the method of initial rates: Initial [NO] Initial rate NO Initial [02] mol mol L-1 mol L-1 L-15-1 0.010 0.010 Experiment 1 Experiment 2 Experiment 3 0.020 0.010 2.5 x 10-5 1.0 x 10-4 5.0...
The reaction C 4 H 8 ( g ) ⟶ 2 C 2 H 4 (...
The reaction C 4 H 8 ( g ) ⟶ 2 C 2 H 4 ( g ) has an activation energy of 262 kJ / mol. At 600.0 K, the rate constant, k , is 6.1 × 10 − 8 s − 1 . What is the value of the rate constant at 835.0 K?
1/ The Following data was obtained while observing a reaction between nitric oxide and hydrogen: F2(g)...
1/ The Following data was obtained while observing a reaction between nitric oxide and hydrogen: F2(g) + 2CLO2(g) -----> 2FCLO2(g) Experiment Initial(F2) Initial(CLO2) Initial rate (mol/L) (mol/L) (mol/L*s) 1/ 0.10 0.010 1.2 x 10^-3 2/ 0.10 0.040 4.8 x 10^-3 3/ 0.20 0.010 2.4 x 10^-3 A/ write the rate law for this reaction B/ calculate the rate constant for the reaction C/ what is the order of this reaction 2/ consider the reaction N2(g) + 3H2(g) ----> 2NH3(g). At...
Consider the following reaction:2 N2O(g) → 2 N2(g)+O2(g)
Consider the following reaction:2 N2O(g) → 2 N2(g)+O2(g)Part AExpress the rate of the reaction in terms of the change in concentration of each of the reactants and products.Express the rate of the reaction in terms of the change in concentration of each of the reactants and products.Rate=12Δ[N2O]Δt=−12Δ[N2]Δt=Δ[O2]ΔtRate=Δ[N2O]Δt=12Δ[N2]Δt=−12Δ[O2]ΔtRate=−Δ[N2O]Δt=−12Δ[N2]Δt=12Δ[O2]ΔtRate=−12Δ[N2O]Δt=12Δ[N2]Δt=Δ[O2]ΔtPart BIn the first 14.0 s of the reaction, 1.9×10−2 mol of O2 is produced in a reaction vessel with a volume of 0.460 L . What is the average rate of the reaction over this time...
The following initial rate information was collected at 25°c for the following reaction: 2H2(g)+2NO(g) N2(g) +2H20(g)...
The following initial rate information was collected at 25°c for the following reaction: 2H2(g)+2NO(g) N2(g) +2H20(g) H2lo (M) INOlo (M) Initial Rate (M/min) 0.0010 0.0020 1.2 x 10-4 0.0010 0.0030 1.8 x 104 0.0020 0.0020 4.8 x 104 Determine the overall order of the reaction and present you answer in numeric torm (le. 0, 1,2 eto)
B1. The following experimental data were obtained for the following reaction at 1000 K: 2 NO(g) + O2(g) 2 NO2(g) NOI (mol L OJ (mol L- Inital rate of reaction (mol L-'s - 0.0100 0.0200 0.0300 0.0200 0.0500 0.0200 3.02 x 10-5 3.02 x 10-4 2.72 x 10-4 (a) Determine the order of the reaction for each reactant (b) Determine the overall order of the reaction. Answer: (c) Calculate the rate constant at this temperature.
4. Suppose the following data is obtained for the reaction: 2NO(g)+2H2(g) → N2(g)+2H20(g) [NO] [Hz] Rate (mol L 54) 0.1 0.1 1.4 x 10-4 0.2 0.1 5.6 x 10-4 0.1 0.2 2.8 x 10-4 Determine the rate law for the reaction
onlocatori entale References The reaction NO(g) +0,() + NO.(k)+(s) plays a role in the formation of titrogen dioxide in automobile engines Suppose a series of experiments measured the rate of this reaction at 500 K and produced the following data NO 101 rate - ANO]/A (01-L) (mol L-4) (mol-1,-1,) 0.00166 0.00415 5.51 x 10-17 0.00166 0.00830 1.10 x 10- 0.00498 0.00415 1.65 x 10-16 Derive a rate law for the reaction (Kate expressions take the general form: rate [ C...
1. The kinetics of the following reaction have been studied: N2
+ 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as
∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1
(a) What is the rate of the reaction in mol L-1 s-1?
(b) What is ∆[N2]/∆t in mol L-1 s-1?
(c) What is ∆[H2]/∆t in mol L-1 s-1?
2. The initial rate of the reaction of species A and B A + 2 B →...
Consider the reaction: 2 NO(g) + O2 (g)--> 2 NO2 (g)
The following data were obtained from three experiments using
the method of initial rates:
3. Consider the reaction: 2 NO(g) + O2(g) → 2 NO2(g) The following data were obtained from three experiments using the method of initial rates: Initial [NO] Initial rate NO Initial [02] mol mol L-1 mol L-1 L-15-1 0.010 0.010 Experiment 1 Experiment 2 Experiment 3 0.020 0.010 2.5 x 10-5 1.0 x 10-4 5.0...
The following initial rate information was collected at 25°c for the following reaction: 2H2(g)+2NO(g) N2(g) +2H20(g) H2lo (M) INOlo (M) Initial Rate (M/min) 0.0010 0.0020 1.2 x 10-4 0.0010 0.0030 1.8 x 104 0.0020 0.0020 4.8 x 104 Determine the overall order of the reaction and present you answer in numeric torm (le. 0, 1,2 eto)
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