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(I know how to get the number answer through a work equation but..I don't know why) If gas expanded from 30L to 70L...

(I know how to get the number answer through a work equation but..I don't know why) If gas expanded from 30L to 70L against a pressure of 2.8atm why would the internal energy be less? Wouldn't the internal energy be the same but more spread out as heat over a larger volume decreasing kinetic energy and there for having a lower pressure, but the same amount of total energy started with is still present within the system.

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Answer #1

If a gas expand against pressure den the area should increase, hence the collision between gas molecules should be less. Hence the internal energy should be less.

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