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8 The Following reaction is classified as: 2HCl(aq) + Ba(OH)2(aq) → BaCl(aq) + 2 H2000 a) oxidation-reduction reaction b) pre
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Answer:-

(8)-

As we know that HCl(aq) is an acid and Ba(OH)2(aq) is a base therefore given reaction is acid-base neutralization reaction in which salt BaCl2(aq) and water (H2O(l)) are formed.

2HCl(aq) + Ba(OH)2(aq)  \rightarrow BaCl2(aq) + 2H2O(l)

Therefore correct option is 'd' i.e acid-base neutralization reaction (i.e the answer).

(9)-

Given:-

volume of NaOH (V1) = 17.50 mL

molarity of NaOH (M1) = 0.1211 M

volume of HNO3 (V2) = 0.1220 M

molarity of HNO3 (M2) = ?

According to the formula

M1V1 = M2V2

So

0.1211 M \times 17.50 mL =   0.1220 M \times V2

volume of HNO3 (V2) = 0.1211 M \times 17.50 mL / 0.1220 M

volume of HNO3 (V2) = 2.11925‬ mL / 0.1220

volume of HNO3 (V2) = 17.37 mL

Therefore correct option is 'a' i.e 17.37 mL (i.e the answer).

(10)-

As we know that Reduction reaction in which an element or ion has tendency to accept the electrons to get reduced. In this reaction, the oxidation state (oxidation no.) of  element or ion is decreased whereas oxidation reaction in which an element or ion has tendency to donate the electrons to get oxidized. In this reaction, the oxidation state (oxidation no.) of  element or ion is increased.

So

(a) -

Cu2+(aq) + 2e- \rightarrow Cu(s) (reduction)

+2 0

(b) -

Cr(s) \rightarrow Cr3+(aq) + 3e- (oxidation)

0 +3

(c) -

Cu+(aq)\rightarrow Cu2+(aq) + e- (oxidation)

+1 +2

(d) -

Fe(s)\rightarrow Fe2+(aq) + e- (oxidation)

0 +2

Therefore correct option is 'a' i.e Cu2+(aq) + 2e- \rightarrow Cu(s)   (i.e the answer).

(11)-

As we know that Reduction reaction in which an element or ion has tendency to accept the electrons to get reduced. In this reaction, the oxidation state (oxidation no.) of  element or ion is decreased therefore this reduced element or ion helps other element or ion to get oxidized and hence such element or ion which reduced are called as oxidizing agent. whereas oxidation reaction in which an element or ion has tendency to donate the electrons to get oxidized. In this reaction, the oxidation state (oxidation no.) of  element or ion is increased. therefore this oxidized element or ion helps other element or ion to get reduced and hence such element or ion which oxidized are called as reducing agent.

So

Ca(s)\rightarrow Ca2+(aq) + 2e- (oxidation) i.e strong reducing agent

Al(s)\rightarrow Al3+(aq) + 3e- (oxidation) i.e moderate reducing agent

Cu(s) \rightarrow Cu2+(aq) + 2e- (oxidation) i.e weak reducing agent

So order of reducing agent is as follows:-

Ca(s)  > Al(s) >   Cu(s)

Also we know that strong reducing agent oxidized weak reducing agent therefore

(b)- Al(s) + Cu2+(aq) (reaction will occur)

strong reducing agent   weak reducing agent

In above Al(s) is strong reducing agent as compared to the Cu2+(aq) (weak reducing agent)

So correct option is 'b' i.e Al(s) +  Cu2+(aq) (i.e the answer).

(12)-

As we know that the combustion reaction of methane (CH4) with oxygen (O2) is as follows:-

CH4(g) + 2O2(g)    \rightarrow CO2(g) + 2H2O (l)

1 mol 2 mol 1 mol 2 mol

16 g 2 \times 32 g 44 g    2 \times 18 g

16 g 64 g 44 g 36 g

As mentioned above

1 mol of CH4 reacts with O2 to produced = 36 g H2O

then

0.533 mol of CH4 reacts with O2 to produced = 0.533 \times 36 g H2O

0.533 mol of CH4 reacts with O2 to produced = 19.19 g H2O which equivalent to the 19.21 g H2O

So correct option is 'c' i.e 19.21 g (i.e the answer).

(13)-

Given:-

volume of NaCl solution (V) = 250 mL = 250 / 1000 L = 0.25 L

molarity of NaCl (M) = 0.365 M = 0.365 mol /L

wt. of NaCl (w) = ?

As we know that

molar mass of NaCl (m) = molar mass of Na + molar mass of Cl

molar mass of NaCl (m) = 23 + 35.5

molar mass of NaCl (m) = 58.5 g / mol

Also we know that

molarity of compound (M) = wt. of compound (w) / molar mass of compound (m) \times volume of compound solution (V) in liter

therefore

wt. of compound (w) =  molarity of compound (M) \times molar mass of compound (m) \times volume of compound solution (V) in liter

So

wt. of NaCl (w) =  molarity of NaCl (M) \times molar mass of NaCl (m) \times volume of NaCl solution (V) in liter

wt. of NaCl (w) =  0.365 mol /L \times 58.5 g / mol  \times 0.25 L

wt. of NaCl (w) =  0.365 mol /L \times 58.5 g / mol  \times 0.25 L

wt. of NaCl (w) = 5.34 g

So correct option is 'a' i.e 5.34 g (i.e the answer).

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