Answer the following for the reaction: NiCl2(aq)+2NaOH(aq)→Ni(OH)2(s)+2NaCl(aq)
A.) How many milliliters of 0.200M NaOH solution are needed to react with 48.0 mL of a 0.240 M NiCl2 solution? Express your answer with the appropriate units.
B.) How many grams of Ni(OH)2 are produced from the reaction of 34.0 mL of a 1.70 M NaOH solution and excess NiCl2? Express your answer with the appropriate units.
C.) What is the molarity of 30.0 mL of a NiCl2 solution that reacts completely with 12.2 mL of a 0.250 M NaOH solution? Express your answer with the appropriate units.
A)
Here:
M(NiCl2)=0.24 M
M(NaOH)=0.2 M
V(NiCl2)=48.0 mL
According to balanced reaction:
2*number of mol of NiCl2 =1*number of mol of NaOH
2*M(NiCl2)*V(NiCl2) =1*M(NaOH)*V(NaOH)
2*0.24 M *48.0 mL = 1*0.2M *V(NaOH)
V(NaOH) = 115.2 mL
Answer: 115 mL
B)
lets calculate the mol of NaOH
volume , V = 34 mL
= 3.4*10^-2 L
use:
number of mol,
n = Molarity * Volume
= 1.7*3.4*10^-2
= 5.78*10^-2 mol
According to balanced equation
mol of Ni(OH)2 produced = (1/2)* moles of NaOH
= (1/2)*5.78*10^-2
= 2.89*10^-2 mol
This is number of moles of Ni(OH)2
Molar mass of Ni(OH)2,
MM = 1*MM(Ni) + 2*MM(O) + 2*MM(H)
= 1*58.69 + 2*16.0 + 2*1.008
= 92.706 g/mol
use:
mass of Ni(OH)2,
m = number of mol * molar mass
= 2.89*10^-2 mol * 92.71 g/mol
= 2.679 g
Answer: 2.68 g
C)
Here:
M(NaOH)=0.25 M
V(NaOH)=12.2 mL
V(NiCl2)=30.0 mL
According to balanced reaction:
1*number of mol of NaOH =2*number of mol of NiCl2
1*M(NaOH)*V(NaOH) =2*M(NiCl2)*V(NiCl2)
1*0.25*12.2 = 2*M(NiCl2)*30.0
M(NiCl2) = 0.0508 M
Answer: 0.0508 M
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