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Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction. Make sure you label w...
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction....
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction. Make sure you label which is least reactive and most reactive. (5 pts) 4. Provide a plausible mechanism for the reaction shown.(6 pts) =100
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction....
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction. Make sure you label which is least reactive and most reactive. (5pts)
2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pas does it have? W...
2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pas does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatie? Explain. (3 pts) Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation fac Make sure you label which is least reactive and most reactive. (5 pts)
Rank each of the following compounds in decreasing order of reactivity towards Friedel-Crafts alkylation. Most reactive...
Rank each of the following compounds in decreasing order of reactivity towards Friedel-Crafts alkylation. Most reactive = 1; if a compound will not react, rank it as "non" rather than assigning a numerical value. Compound A: bromobenzene Compound B: aniline Compound C: anisole Compound D: iodobenzene
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp? hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Dec 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 3. Rank the reactivity of the compounds...
12. Identify which ammonium ion has the lower pka. Use aromaticity concepts to explain your answers.(3pts)...
12. Identify which ammonium ion has the lower pka. Use aromaticity concepts to explain your answers.(3pts) 13. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 14. The rate of solvolysis of iodide 1 is 100 times faster than the rate of solvolysis of iodide 3. What explanation (with structures) can you provide for...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Antanan ENon ordre Energy Bunding aromatic antiaromatic 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) nonovomatic...
4. Provide a plausible mechanism for the reaction shown. (6 pts) 7 NaNH. Hycor ND 5....
4. Provide a plausible mechanism for the reaction shown. (6 pts) 7 NaNH. Hycor ND 5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reagents Reagents A! Reagents D-7 Reagents Reagents 6. Predict the products from the Birch reductions shown below. (3 pts) Nz, NHU CH OH Bonus: (6 pts) Provide a synthesis for the target molecule using benzene. CO2H CO2H TM 1. Draw Frost circle diagrams for each compound shown....
Can you please answer all of them? Section B: Free Response (you must show your work...
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
When performing a Friedel-Crafts alkylation reaction, not only does one have the problems of multiple alkylation...
When performing a Friedel-Crafts alkylation reaction, not only does one have the problems of multiple alkylation and rearrangement of the cation, but the presence of strong electron donating groups(yes, donating is correct) prevents reaction. Provide an explanation for this. Metallocenes, like ferrocene cannot be nitrated. Why? Draw the structure of the diacetylferrocene you would obtain if ferrocene were diacetylated. Draw an arrow pushing mechanism for the formation of the acylium ion when acetic anhydride reacts with phosphoric acid. Provide the...
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction. Make sure you label which is least reactive and most reactive. (5 pts) 4. Provide a plausible mechanism for the reaction shown.(6 pts) =100
3. Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation reaction. Make sure you label which is least reactive and most reactive. (5pts)
2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pas does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatie? Explain. (3 pts) Rank the reactivity of the compounds shown below when using a Friedel Crafts alkylation fac Make sure you label which is least reactive and most reactive. (5 pts)
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp? hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Dec 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 3. Rank the reactivity of the compounds...
12. Identify which ammonium ion has the lower pka. Use aromaticity concepts to explain your answers.(3pts) 13. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) 14. The rate of solvolysis of iodide 1 is 100 times faster than the rate of solvolysis of iodide 3. What explanation (with structures) can you provide for...
1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) Antanan ENon ordre Energy Bunding aromatic antiaromatic 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect this molecule to be aromatic, antiaromatic or non aromatic? Explain. (3pts) nonovomatic...
4. Provide a plausible mechanism for the reaction shown. (6 pts) 7 NaNH. Hycor ND 5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reagents Reagents A! Reagents D-7 Reagents Reagents 6. Predict the products from the Birch reductions shown below. (3 pts) Nz, NHU CH OH Bonus: (6 pts) Provide a synthesis for the target molecule using benzene. CO2H CO2H TM 1. Draw Frost circle diagrams for each compound shown....
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
When performing a Friedel-Crafts alkylation reaction, not only does one have the problems of multiple alkylation and rearrangement of the cation, but the presence of strong electron donating groups(yes, donating is correct) prevents reaction. Provide an explanation for this. Metallocenes, like ferrocene cannot be nitrated. Why? Draw the structure of the diacetylferrocene you would obtain if ferrocene were diacetylated. Draw an arrow pushing mechanism for the formation of the acylium ion when acetic anhydride reacts with phosphoric acid. Provide the...
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