Answer B
This is based on "Nitrogen Rule" which states that molecules having odd number of nitrogen will have odd m/z values and molecule having even number of nitrogen will have even m/z values
Note : molecules which does not have nitrogen should be counted as '0' nitrogen which is again a even number hence its m/z will also be even
so among the choices 1 and 4 contains 0 nitrogen hence even
Option 3 contains 2 nitrogen which is even
only option left is option B which contain 1 nitrogen which is odd hence it will have odd m/z values
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